DIIMINOPHOSPHINATES OF LITHIUM, SAMARIUM AND YTTERBIUM - MOLECULAR-STRUCTURES LI[PH2P(NSIME3)2](THF)2 AND [PH2P(NSIME3)2]2SM(MU-I)2LI(THF)2

被引：69

作者：

RECKNAGEL, A ^{[1
]}

STEINER, A ^{[1
]}

NOLTEMEYER, M ^{[1
]}

BROOKER, S ^{[1
]}

STALKE, D ^{[1
]}

EDELMANN, FT ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 414卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86331-J

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The molecular structure of Li[Ph2P(NSiMe3)2]THF)2 (2) has been determined by an X-ray diffraction study. A four-membered LiNPN ring forms the central unit of the monomeric molecule. YbI2 reacts with two equivalents of Li[Ph2P(NSiMe3)2] (1) to give the novel ytterbium(II)diiminophosphinate [Ph2P(NSiMe3)2]2Yb(THF)2 (3). A similar reaction of 1 with SmI2 affords the samarium(III) derivative [Ph2P(NSiMe3)2]2Sm(mu-1)2Li(THF)2 (4) whose structure has also been determined by an X-ray diffraction study.

引用

页码：327 / 335

页数：9

共 21 条

[1] THE 1ST HIGH-RESOLUTION DIRECT NMR OBSERVATION OF AN F-BLOCK ELEMENT [J].

AVENT, AG ;

EDELMAN, MA ;

LAPPERT, MF ;

LAWLESS, GA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (09) :3423-3425

[2] PREPARATION OF N,N,N'-TRIS(TRIMETHYLSILYL)AMIDINES - A CONVENIENT ROUTE TO UNSUBSTITUTED AMIDINES [J].

BOERE, RT ;

OAKLEY, RT ;

REED, RW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 331 (02) :161-167

[3] SOLUTION SYNTHESIS AND CRYSTALLOGRAPHIC CHARACTERIZATION OF THE DIVALENT ORGANOSAMARIUM COMPLEXES (C5ME5)2SM(THF)2 AND [(C5ME5)SM(MU-I)(THF)2]2 [J].

EVANS, WJ ;

GRATE, JW ;

CHOI, HW ;

BLOOM, I ;

HUNTER, WE ;

ATWOOD, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (04) :941-946

[4] REDUCTIVE COUPLING OF PYRIDAZINE AND BENZALDEHYDE AZINE AND REDUCTION OF BIPYRIDINE BY (C5ME5)2SM(THF)2 [J].

EVANS, WJ ;

DRUMMOND, DK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (09) :3329-3335

[5] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF BIS(PENTAMETHYLCYCLOPENTADIENYL) LANTHANIDE AND YTTRIUM HALIDE-COMPLEXES [J].

EVANS, WJ ;

GRATE, JW ;

LEVAN, KR ;

BLOOM, I ;

PETERSON, TT ;

DOEDENS, RJ ;

ZHANG, HM ;

ATWOOD, JL .

INORGANIC CHEMISTRY, 1986, 25 (20) :3614-3619

[6]

KNOSEL F, 1989, Z NATURFORSCH B, V44, P1171

[7]

NAMY JL, 1981, NOUV J CHIM, V5, P479

[8]

NAMY JL, 1977, NOUV J CHIM, V1, P5

[9] SYNTHETIC, X-RAY STRUCTURAL, AND PHOTOLUMINESCENCE STUDIES ON PENTAMETHYLCYCLOPENTADLENYL DERIVATIVES OF LANTHANUM, CERIUM, AND PRASEODYMIUM [J].

RAUSCH, MD ;

MORIARTY, KJ ;

ATWOOD, JL ;

WEEKS, JA ;

HUNTER, WE ;

BRITTAIN, HG .

ORGANOMETALLICS, 1986, 5 (06) :1281-1283

[10] SYNTHESIS OF METALLACYCLOPHOSPHAZENES WITH PRASEODYMIUM, NEODYMIUM, URANIUM AND THORIUM [J].

RECKNAGEL, A ;

WITT, M ;

EDELMANN, FT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 371 (03) :C40-C44

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