A NOVEL TI(0) INDUCED ALLYLATION OF IMINES IN A TICL4 (CAT) AL BIMETAL SYSTEM - CHIRALITY TRANSFER OF L-VALINE TO HOMOALLYLAMINE

被引：67

作者：

TANAKA, H ^{[1
]}

INOUE, K ^{[1
]}

POKORSKI, U ^{[1
]}

TANIGUCHI, M ^{[1
]}

TORII, S ^{[1
]}

机构：

[1] OKAYAMA UNIV,FAC ENGN,DEPT APPL CHEM,OKAYAMA 700,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 21期

关键词：

D O I：

10.1016/S0040-4039(00)89015-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

"Barbier Type" allylation of imines with allyl bromide has been performed successfully by the action of aluminum (1 equiv.) and titanium(IV)chloride (0.05 equiv.) in THF. The chirality transfer of α-amino acid esters to homoallyl amines is demonstrated by allylation of N-benzalvaline methyl ester followed by alkaline hydrolysis and electrolytic decarboxylation. © 1990.

引用

页码：3023 / 3026

页数：4

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