Model for chemical reaction kinetics in perchloric acid-ammonia flames

被引：20
作者：
Ermolin, NE
机构：
来源：
COMBUSTION EXPLOSION AND SHOCK WAVES | 1995年 / 31卷 / 05期
关键词：
D O I：
10.1007/BF00743807
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
We continue the study begun in [1, 2] of chemical processes in perchloric acid-ammonia flames. We propose new channels for the reaction. Based on experimental data on the chemical structure of an ammonium perchlorate flame and flames in O-2/NH3/Ar, NH3/HClO4/H2O/Ar mixtures, we estimate the rate constants for steps that have not been well studied and refine the kinetic mechanism of [1, 2]. We discuss calculation results for the chemical structure of a flame in an NH3/HClO4/H2O/Ar mixture and an ammonium perchlorate flame. We simplify the kinetic mechanism.
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页码：555 / 565
页数：11
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