WAVE-PACKET STUDIES OF THE VIBRATIONAL PREDISSOCIATION OF 3-ATOM AND 4-ATOM VAN-DER-WAALS COMPLEXES

被引：24
作者：
GRAY, SK
机构：
来源：
FARADAY DISCUSSIONS | 1994年 / 97卷
关键词：
D O I：
10.1039/fd9949700143
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Vibrational predissociation of XI(2) and X(2)I(2) Van der Waals complexes, with X = He and Ne, is studied with wave packets. Three-dimensional calculations are carried out on the three-atom systems. Suitable X...I potential interactions are determined and product distributions are predicted. Reduced dimension models of X(2)I(2)(upsilon') --> 2X + I-2(upsilon < upsilon') are investigated. Comparison is made with available experimental results. Mechanistic issues, including the role of intramolecular vibrational relaxation resonances, are addressed.
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页码：143 / 154
页数：12
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