MOLECULAR INTERPRETATION OF THE LINEAR RELATIONSHIP BETWEEN THE ENTROPY AND THE ENTHALPY OF ACTIVATION OF CHARGE-TRANSFER REACTIONS IN POLAR LIQUIDS

被引：0

作者：

CHANDRA, A ^{[1
]}

BAGCHI, B ^{[1
]}

机构：

[1] INDIAN INST SCI, SOLID STATE & STRUCT CHEM UNIT, BANGALORE 560012, KARNATAKA, INDIA

来源：

PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES | 1992年 / 104卷 / 03期

关键词：

MOLECULAR INTERPRETATION; LINEAR RELATIONSHIP; ENTROPY; ENTHALPY OF ACTIVATION; POLAR LIQUIDS; CHARGE TRANSFER REACTIONS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The well-known linear relationship (T-DELTA-S# = alpha-DELTA-H# + beta, where 1 > alpha > 0, beta > 0) between the entropy (DELTA-S#) and the enthalpy (DELTA-H#) of activation for reactions in polar liquids is investigated by using a molecular theory. An explicit derivation of this linear relation from first principles is presented for an outersphere charge transfer reaction. The derivation offers microscopic interpretation for the quantities-alpha and beta. It has also been possible to make connection with and justify the arguments of Bell put forward many years ago.

引用

页码：399 / 407

页数：9