PREPARATION OF C-AXIS-ORIENTED BI4TI3O-12 THIN-FILMS BY METALORGANIC CHEMICAL-VAPOR-DEPOSITION

被引:95
作者
NAKAMURA, T [1 ]
MUHAMMET, R [1 ]
SHIMIZU, M [1 ]
SHIOSAKI, T [1 ]
机构
[1] KYOTO UNIV,FAC ENGN,DEPT ELECTR,KYOTO 606,JAPAN
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 1993年 / 32卷 / 9B期
关键词
FERROELECTRIC THIN FILMS; BISMUTH TITANATE; MOCVD; BUFFER LAYER; BI(C6H-5)3; D-E HYSTERESIS;
D O I
10.1143/JJAP.32.4086
中图分类号
O59 [应用物理学];
学科分类号
摘要
Bi4Ti3O12 thin films were prepared on Pt/SiO2/Si(100), Pt/Ti/SiO2/Si(100) and sapphire (R-cut) by metalorganic chemical vapor deposition (MOCVD). Bi(C6H5)3 and Ti(i-OC3H7)4 were chosen as the metalorganic precursors. C-axis-oriented Bi4Ti3O12 thin films were grown on Pt/SiO2/Si (100) at 550-degrees-C. These films deposited directly on the substrates exhibit high loss and exhibit very rough surface morphology. However, a Bi4Ti3O12 film with a Bi2Ti2O7 buffer layer on Pt/SiO2/Si(100) exhibits very smooth morphology and are highly c-axis-oriented. This film shows remanent polarization of 0.6 muC/cm2, coercive field of 13 kV/cm and dielectric constant of 180.
引用
收藏
页码:4086 / 4088
页数:3
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