ARYL HALIDES AS CONVENIENT PRECURSORS OF ELECTROGENERATED BASES - EFFICIENT SYNTHESES OF BETA-OXO NITRILES OR ESTERS BY COUPLING ACTIVE-HYDROGEN GROUPS WITH ESTERS

被引：14

作者：

BARHDADI, R ^{[1
]}

GAL, J ^{[1
]}

HEINTZ, M ^{[1
]}

TROUPEL, M ^{[1
]}

机构：

[1] CNRS,UMR 28,ELECTROCHIM CATALYSE & SYNTH ORGAN LAB,2 RUE HENRI DUNANT,F-94320 THIAIS,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 01期

关键词：

D O I：

10.1039/c39920000050

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In an undivided cell fitted with a sacrificial anode and a nickel cathode on which cadmium had been deposited, the electroreduction of aromatic halides affords a strong base which allows the effective synthesis of beta-oxo nitriles or beta-oxo esters from the coupling of active-hydrogen compounds with esters.

引用

页码：50 / 51

页数：2

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