CS3[TB10(C2)2]CL2, A NEW FORMULA AND STRUCTURE TYPE WITH ISOLATED DIMERIC CLUSTERS

被引：11

作者：

ARTELT, HM ^{[1
]}

MEYER, G ^{[1
]}

机构：

[1] UNIV HANNOVER,INST ANORGAN CHEM,CALLINSTR 9,D-30167 HANNOVER,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 09期

关键词：

TERBIUM CLUSTER; TB10(C2)2; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19946200906

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cs[Tb10(C2)2]Cl21 is obtained via the metallothermic reduction of TbCl3 with caesium in the presence of graphite as black single crystals. The crystal structure (monoclinic, C2/c, Z = 4; a = 2318.72(13); b = 1245.8(9); c = 1502.0(13) pm; beta = 98.13(6)-degrees; R = 0.089; R(w) = 0.049) contains dimeric clusters that are built from two octahedra connected via one common edge and filled with C2 units. These isolated [Tb10(C2)2] clusters are surrounded by 26 chloride ligands which are then connected via i-a and a-a bridges in a way that voids for Cs+ of coordination number 10 are formed.

引用

页码：1527 / 1531

页数：5

共 29 条

[1] ADACHI GY, 1991, HDB PHYSICS CHEM RAR, V15
[2] SYNTHESIS AND CRYSTAL-STRUCTURES OF 2 NEW REDUCED IODIDES OF ERBIUM WITH ISOLATED MONOMERIC AND DIMERIC CLUSTERS, CS[ER6C]I12 AND CS[ER10(C2)2]I18
ARTELT, HM
MEYER, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (18) : 1320 - 1321
[3] CS4[SC6C]CL13 AND CS4[PR6(C2)]I13 - 2 EXAMPLES FOR THE MISSING LINK IN THE CONNECTIVITY OF [M6Z]X(12(I)X(6)(A) BUILDING UNITS
ARTELT, HM
SCHLEID, T
MEYER, G
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (09): : 1521 - 1526
[4] CS-2[PR-6(C-2)I-12 - THE 1ST QUATERNARY REDUCED HALIDE WITH ISOLATED [M-6(C-2)] CLUSTERS
ARTELT, HM
MEYER, G
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (01): : 1 - 6
[5] ARTELT HM, 1992, Z ANORG ALLG CHEM, V618, P18
[6] Cheetham A.K., 1992, SOLID STATE CHEM COM
[7] CORBETT JD, 1983, INORG SYN, V22, P15
[8] CORBETT JD, 1992, PURE APPL CHEM
[9] CORBETT JD, 1992, NATO ASI SERIES
[10] RELATIVISTIC CALCULATION OF ANOMALOUS SCATTERING FACTORS FOR X-RAYS
CROMER, DT
LIBERMAN, D
[J]. JOURNAL OF CHEMICAL PHYSICS, 1970, 53 (05) : 1891 - &

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