TAILOR-MAKING OF DESIRED ASSEMBLIES FROM WELL-DESIGNED MONOMERS - USE OF CALIX[4]ARENE CONFORMERS AS BUILDING-BLOCKS

被引：23

作者：

ARIMORI, S ^{[1
]}

NAGASAKI, T ^{[1
]}

SHINKAI, S ^{[1
]}

机构：

[1] KYUSHU UNIV,FAC ENGN,DEPT ORGAN SYNTH,FUKUOKA 812,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 08期

关键词：

D O I：

10.1039/p19930000887

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Water-soluble, conformationally-immobilized calix[4]arenes with cone and 1,3-alternate conformations (cone-1 and 1,3-alternate-1, respectively) have been synthesized. In aqueous solution cone-1, with a cone-shaped surface, aggregated into micelles with 20-40 angstrom diameter whereas 1,3-alternate-1, with a cylindrical surface, could not form such aggregates for concentrations up to 0.010 mol dm-3.

引用

页码：887 / 889

页数：3

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