SYNTHESIS OF (+/-) FREDERICAMYCIN-A

被引：32

作者：

RAO, AVR

SINGH, AK

RAO, BV

REDDY, KM

机构：

[1] Indian Institute of Chemical Technology, Hyderabad

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 16期

关键词：

D O I：

10.1016/S0040-4039(00)77651-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of Fredericamycin A (1) has been achieved by subjecting the 1,3-dione (14) to an unusual 5-endo trigonal radical cyclization followed by reductive elimination of the halogen in 15 and subsequent demethylation.

引用

页码：2665 / 2668

页数：4

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