1,8-BIS(DIPHENYLPHOSPHINO)NAPHTHALENE - A RIGID CHELATING, DIPHOSPHINE ANALOG OF PROTON SPONGE

被引：97

作者：

JACKSON, RD ^{[1
]}

JAMES, S ^{[1
]}

ORPEN, AG ^{[1
]}

PRINGLE, PG ^{[1
]}

机构：

[1] UNIV BRISTOL,SCH CHEM,CANTOCKS CLOSE,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 458卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80482-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of the new diphosphine, 1,8-bis(diphenylphosphino) naphthalene (1a), and its X-ray crystal structure are reported. Protonation of 1a gives a fluxional species to which a P-P bonded structure is assigned. Despite the strain apparent in the solid state due to the proximity of the diphenylphosphino groups, it appears that 1a has a normal coordination chemistry with platinum(II) and palladium(II).

引用

页码：C3 / C4

页数：2

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