MOLECULAR-COMPLEXES OF CYCLOPHANES .18. SPECTROSCOPIC AND THERMODYNAMIC STUDIES ON THE CHARGE-TRANSFER COMPLEXES BETWEEN 4-([2.2]PARACYCLOPHANOYL)AMINES AND PI-ACCEPTORS

被引：6
作者：
ALY, AA
HASSAN, AA
MOHAMED, YS
MOURAD, AFE
HOPF, H
机构：
[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ORGAN CHEM,W-3300 BRAUNSCHWEIG,GERMANY
[2] MENIA UNIV,FAC SCI,DEPT CHEM,MENIA,EGYPT
来源：
MONATSHEFTE FUR CHEMIE | 1992年 / 123卷 / 1-2期
关键词：
CYCLOPHANES; MOLECULAR COMPLEXES; CHARGE-TRANSFER COMPLEXES;
D O I：
10.1007/BF01045309
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The charge-transfer (CT) complexes of several substituted 4-([2.2]paracyclophanoyl)amines as donors with tetracyanoethylene (TCNE) and 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) as pi-acceptors have been studied spectrophotometrically. The role of the molecular structure of the donors on their Lewis basicities, the site and type of CT interactions are discussed. The thermodynamic properties of some CT complexes as well as the solvent effect on the CT complexation are reported.
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页码：179 / 189
页数：11
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