5-METHYLENE-2(5H)-FURANONE IN DIELS-ALDER REACTIONS WITH CYCLIC DIENES - ENDO/EXO SELECTIVITY

被引：13

作者：

ALONSO, D ^{[1
]}

BRANCHADELL, V ^{[1
]}

FONT, J ^{[1
]}

OLIVA, A ^{[1
]}

ORTUNO, RM ^{[1
]}

SANCHEZFERRANDO, F ^{[1
]}

机构：

[1] UNIV AUTONOMA BARCELONA,DEPT QUIM,E-08193 BARCELONA,SPAIN

来源：

TETRAHEDRON | 1990年 / 46卷 / 12期

关键词：

D O I：

10.1016/S0040-4020(01)86771-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Endo/exo selectivity in the reactions of 5-methylene-2(5H)-furanone, 1, with cyclic dienes has been investigated. Both the kinetic and theoretical studies of the cycloaddition between 1 and cyclopentadiene have permitted to explain the observed selectivity as a direct consequence of a kinetic control over the process. © 1990.

引用

页码：4371 / 4378

页数：8

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