6-DEOXY-6-N-HISTAMINO-BETA-CYCLODEXTRIN COPPER(II) COMPLEX, A NEW ENANTIOSELECTIVE RECEPTOR FOR AROMATIC-AMINO-ACIDS

被引：74

作者：

IMPELLIZZERI, G ^{[1
]}

MACCARRONE, G ^{[1
]}

RIZZARELLI, E ^{[1
]}

VECCHIO, G ^{[1
]}

CORRADINI, R ^{[1
]}

MARCHELLI, R ^{[1
]}

机构：

[1] UNIV CATANIA,DIPARTIMENTO SCI CHIM,VIALE A DORIA 6,I-95125 CATANIA,ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 10期

关键词：

D O I：

10.1002/anie.199113481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral recognition of D- and L-tryptophan in the mobile phase in the presence of the title complex [CuL]2+ is the reason for their successful HPLC separation on a conventional achiral reversed-phase column. The separation is based on mixed inclusion-ligand-exchange chromatography, in which the more stable complex [CuL(D-Trp)]+ probably has the form shown here.

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页码：1348 / 1349

页数：2

相关论文

共 11 条

[1] BIS(L-AMINO ACID AMIDATO)COPPER(II) COMPLEXES AS CHIRAL ELUENTS IN THE ENANTIOMERIC SEPARATION OF D,L-DANSYLAMINO ACIDS BY REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY [J].

ARMANI, E ;

BARAZZONI, L ;

DOSSENA, A ;

MARCHELLI, R .

JOURNAL OF CHROMATOGRAPHY, 1988, 441 (02) :287-298

[2] CONFORMATIONAL FEATURES AND COORDINATION PROPERTIES OF FUNCTIONALIZED CYCLODEXTRINS - FORMATION, STABILITY, AND STRUCTURE OF PROTON AND COPPER(II) COMPLEXES OF HISTAMINE-BEARING BETA-CYCLODEXTRIN IN AQUEOUS-SOLUTION [J].

BONOMO, RP ;

CUCINOTTA, V ;

DALESSANDRO, F ;

IMPELLIZZERI, G ;

MACCARRONE, G ;

VECCHIO, G ;

RIZZARELLI, E .

INORGANIC CHEMISTRY, 1991, 30 (13) :2708-2713

[3] NONCOVALENT INTERACTIONS IN THERMODYNAMIC STEREOSELECTIVITY OF MIXED-LIGAND COPPER(II)-D-HISTIDINE OR L-HISTIDINE COMPLEXES WITH L-AMINO-ACIDS - A POSSIBLE MODEL OF METAL ION-ASSISTED MOLECULAR RECOGNITION [J].

BORGHESANI, G ;

PULIDORI, F ;

REMELLI, M ;

PURRELLO, R ;

RIZZARELLI, E .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (07) :2095-2100

[4]

DAVANKOV VA, 1983, ADV CHROMATOGR, V22, P71

[5] SUPERQUAD - AN IMPROVED GENERAL PROGRAM FOR COMPUTATION OF FORMATION-CONSTANTS FROM POTENTIOMETRIC DATA [J].

GANS, P ;

SABATINI, A ;

VACCA, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (06) :1195-1200

[6] SEPARATION OF D-AMINO AND L-AMINO-ACIDS BY LIQUID-CHROMATOGRAPHY - USE OF CHIRAL ELUANTS [J].

HARE, PE ;

GILAV, E .

SCIENCE, 1979, 204 (4398) :1226-1228

[7] GAS-CHROMATOGRAPHIC SEPARATION OF ENANTIOMERS ON OPTICALLY-ACTIVE METAL-COMPLEX-FREE STATIONARY PHASES .2. GAS-CHROMATOGRAPHIC SEPARATION OF ENANTIOMERS ON CYCLODEXTRIN DERIVATIVES [J].

SCHURIG, V ;

NOWOTNY, HP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1990, 29 (09) :939-957

[8]

SCHURIG V, 1990, ANGEW CHEM, V102, P969

[9] CYCLODEXTRIN FLEXIBLY CAPPED WITH METAL-ION [J].

TABUSHI, I ;

SHIMIZU, N ;

SUGIMOTO, T ;

SHIOZUKA, M ;

YAMAMURA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (21) :7100-7102

[10] ARTIFICIAL RECEPTORS FOR AMINO-ACIDS IN WATER - LOCAL ENVIRONMENTAL-EFFECT ON POLAR RECOGNITION BY 6A-AMINO-6B-CARBOXY-CYCLODEXTRINS AND 6B-AMINO-6A-CARBOXY-BETA-CYCLODEXTRINS [J].

TABUSHI, I ;

KURODA, Y ;

MIZUTANI, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (15) :4514-4518