6-DEOXY-6-N-HISTAMINO-BETA-CYCLODEXTRIN COPPER(II) COMPLEX, A NEW ENANTIOSELECTIVE RECEPTOR FOR AROMATIC-AMINO-ACIDS

被引：74

作者：

IMPELLIZZERI, G ^{[1
]}

MACCARRONE, G ^{[1
]}

RIZZARELLI, E ^{[1
]}

VECCHIO, G ^{[1
]}

CORRADINI, R ^{[1
]}

MARCHELLI, R ^{[1
]}

机构：

[1] UNIV CATANIA,DIPARTIMENTO SCI CHIM,VIALE A DORIA 6,I-95125 CATANIA,ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 10期

关键词：

D O I：

10.1002/anie.199113481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral recognition of D- and L-tryptophan in the mobile phase in the presence of the title complex [CuL]2+ is the reason for their successful HPLC separation on a conventional achiral reversed-phase column. The separation is based on mixed inclusion-ligand-exchange chromatography, in which the more stable complex [CuL(D-Trp)]+ probably has the form shown here.

引用

页码：1348 / 1349

页数：2

共 11 条

[1] BIS(L-AMINO ACID AMIDATO)COPPER(II) COMPLEXES AS CHIRAL ELUENTS IN THE ENANTIOMERIC SEPARATION OF D,L-DANSYLAMINO ACIDS BY REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY
ARMANI, E
BARAZZONI, L
DOSSENA, A
MARCHELLI, R
[J]. JOURNAL OF CHROMATOGRAPHY, 1988, 441 (02): : 287 - 298
[2] CONFORMATIONAL FEATURES AND COORDINATION PROPERTIES OF FUNCTIONALIZED CYCLODEXTRINS - FORMATION, STABILITY, AND STRUCTURE OF PROTON AND COPPER(II) COMPLEXES OF HISTAMINE-BEARING BETA-CYCLODEXTRIN IN AQUEOUS-SOLUTION
BONOMO, RP
CUCINOTTA, V
DALESSANDRO, F
IMPELLIZZERI, G
MACCARRONE, G
VECCHIO, G
RIZZARELLI, E
[J]. INORGANIC CHEMISTRY, 1991, 30 (13) : 2708 - 2713
[3] NONCOVALENT INTERACTIONS IN THERMODYNAMIC STEREOSELECTIVITY OF MIXED-LIGAND COPPER(II)-D-HISTIDINE OR L-HISTIDINE COMPLEXES WITH L-AMINO-ACIDS - A POSSIBLE MODEL OF METAL ION-ASSISTED MOLECULAR RECOGNITION
BORGHESANI, G
PULIDORI, F
REMELLI, M
PURRELLO, R
RIZZARELLI, E
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (07): : 2095 - 2100
[4] DAVANKOV VA, 1983, ADV CHROMATOGR, V22, P71
[5] SUPERQUAD - AN IMPROVED GENERAL PROGRAM FOR COMPUTATION OF FORMATION-CONSTANTS FROM POTENTIOMETRIC DATA
GANS, P
SABATINI, A
VACCA, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (06): : 1195 - 1200
[6] SEPARATION OF D-AMINO AND L-AMINO-ACIDS BY LIQUID-CHROMATOGRAPHY - USE OF CHIRAL ELUANTS
HARE, PE
GILAV, E
[J]. SCIENCE, 1979, 204 (4398) : 1226 - 1228
[7] GAS-CHROMATOGRAPHIC SEPARATION OF ENANTIOMERS ON OPTICALLY-ACTIVE METAL-COMPLEX-FREE STATIONARY PHASES .2. GAS-CHROMATOGRAPHIC SEPARATION OF ENANTIOMERS ON CYCLODEXTRIN DERIVATIVES
SCHURIG, V
NOWOTNY, HP
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1990, 29 (09) : 939 - 957
[8] SCHURIG V, 1990, ANGEW CHEM, V102, P969
[9] CYCLODEXTRIN FLEXIBLY CAPPED WITH METAL-ION
TABUSHI, I
SHIMIZU, N
SUGIMOTO, T
SHIOZUKA, M
YAMAMURA, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (21) : 7100 - 7102
[10] ARTIFICIAL RECEPTORS FOR AMINO-ACIDS IN WATER - LOCAL ENVIRONMENTAL-EFFECT ON POLAR RECOGNITION BY 6A-AMINO-6B-CARBOXY-CYCLODEXTRINS AND 6B-AMINO-6A-CARBOXY-BETA-CYCLODEXTRINS
TABUSHI, I
KURODA, Y
MIZUTANI, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (15) : 4514 - 4518

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