(BEDT-TTF)2GACL4 - STRUCTURE, ELECTRICAL AND MAGNETIC-PROPERTIES

被引：10
|
作者：
KURMOO, M
ALLAN, M
FRIEND, RH
CHASSEAU, D
BRAVIC, G
DAY, P
机构：
[1] INST LAUE LANGEVIN,F-33042 GRENOBLE,FRANCE
[2] UNIV BORDEAUX 1,CRISTALLOG LAB,F-33405 TALENCE,FRANCE
[3] UNIV CAMBRIDGE,CAVENDISH LAB,CAMBRIDGE CB3 0HE,ENGLAND
来源：
SYNTHETIC METALS | 1991年 / 42卷 / 1-2期
关键词：
D O I：
10.1016/0379-6779(91)92032-D
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
We report the synthesis, crystal structure, electrical transport and magnetic properties of (BEDT-TTF)2GaCl4. It crystallises in a triclinic system, P1BAR, a = 31.911, b = 16.580, c = 6.645 angstrom, alpha = 98.15, beta = 85.60, gamma = 90.55-degrees, Z = 4 and V = 3470 angstrom 3 with stacks of twisted dimers. sigma-RT (parallel-to to c) = 0.1 Scm-1 and E(A) = 0.21 eV. The susceptibility is anisotropic; chi-(parallel-to to c) behaves as a 1D antiferromagnetic chain and chi-(perpendicular-to to c) is activated with E(A) approximately 9meV.
引用
收藏
页码：2127 / 2130
页数：4
相关论文
共 50 条
  • [21] Electrical and spectral properties of organic salts formed from BEDT-TTF and magnetic anions
    Graja, A
    Lapinski, A
    Starodub, VA
    MACROMOLECULAR SYMPOSIA, 2004, 212 : 169 - 178
  • [22] Structure and electrical conductivity of (BEDT-TTF)2HgCl3 • TCE
    Liu, Z
    Fang, Q
    Yu, WT
    Chen, SH
    Jiang, MH
    Zhang, B
    Zhang, JB
    Zhu, DB
    SYNTHETIC METALS, 2000, 114 (03) : 243 - 250
  • [23] THE BAND ELECTRONIC-STRUCTURES OF (BEDT-TTF)2BRO4- AND (BEDT-TTF)2REO4-
    WHANGBO, MH
    BENO, MA
    LEUNG, PCW
    EMGE, TJ
    WANG, HH
    WILLIAMS, JM
    SOLID STATE COMMUNICATIONS, 1986, 59 (12) : 813 - 818
  • [24] The crystal structure of (BEDT-TTF)4[Ni(CN)4]
    Tanaka, Masashi, 1600, Chemical Society of Japan (64):
  • [25] MAGNETIC-PROPERTIES OF BEDT-TTF RADICAL-ION SALTS WITH KEGGIN-TYPE POLYOXOMETALATES
    GOMEZGARCIA, CJ
    GIMENEZSAIZ, C
    TRIKI, S
    CORONADO, E
    DUCASSE, L
    LEMAGUERES, P
    OUAHAB, L
    DELHAES, P
    SYNTHETIC METALS, 1995, 70 (1-3) : 783 - 784
  • [26] Crystal structure and magnetism of (BEDT-TTF)(2)MCl(4) (BEDT-TTF equals bis(ethylenedithio)tetrathiafulvalene; M=Ga, Fe)
    Kurmoo, M
    Day, P
    Guionneau, P
    Bravic, G
    Chasseau, D
    Ducasse, L
    Allan, ML
    Marsden, ID
    Friend, RH
    INORGANIC CHEMISTRY, 1996, 35 (16) : 4719 - 4726
  • [27] ELECTRICAL ANISOTROPY OF ALPHA-(BEDT-TTF)(2)KHG(SCN)(4)
    ARIFUKU, M
    TAJIMA, H
    OHTA, T
    TOKUMOTO, M
    KINOSHITA, N
    ANZAI, H
    SYNTHETIC METALS, 1995, 70 (1-3) : 827 - 828
  • [28] Transport properties of α″-phase organic conductors, (BEDT-TTF)2 CsHg(SCN)4 and (BEDT-TTF)2K1.4Co(SCN)4
    Hanazato, Shingo
    Mori, Takehiko
    Mori, Hatsumi
    Tanaka, Shoji
    Physica C: Superconductivity and its Applications, 1999, 316 (03): : 243 - 250
  • [29] Superconducting Phase in λ-(BEDT-STF)2GaCl4 at High Pressures
    Minamidate, Takaaki
    Oka, Yuki
    Shindo, Hironori
    Yamazaki, Toshitaka
    Matsunaga, Noriaki
    Nomura, Kazushige
    Kawamoto, Atsushi
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2015, 84 (06)
  • [30] A new compound in the BEDT-TTF family [BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene] with a tetrathiocyanatocuprate(II) anion, (BEDT-TTF)(4)[Cu(NCS)(4)]
    Faulmann, Christophe
    Cormary, Benoit
    Valade, Lydie
    Jacob, Kane
    de Caro, Dominique
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1755 - +
12345