INFLUENCE OF WATER ON THE KINETICS OF THE REACTION OF NITROALKANES WITH AMINE BASES IN APROTIC-SOLVENTS

被引：0

作者：

GALEZOWSKI, W ^{[1
]}

JARCZEWSKI, A ^{[1
]}

机构：

[1] ADAM MICKIEWICZ UNIV,DEPT CHEM,GRUNWALDZKA 6,PL-60780 POZNAN,POLAND

来源：

ACTA CHIMICA HUNGARICA-MODELS IN CHEMISTRY | 1990年 / 127卷 / 05期

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D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The traces of water in reaction systems of nitroalkanes and amine bases in aprotic solvents caused a marked decrease of the reaction rate instead of its acceleration expected from possible triggering of side reactions effected by hydroxide ions or hydroxide ion pairs BH+, OH-. The kinetics and possible consequences in the mechanism of proton transfer are discussed.

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页码：679 / 688

页数：10

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