SYNTHESIS OF ZIRCONIUM-OXIDE BY HYDROLYSIS OF ZIRCONIUM ALKOXIDE

被引：28
作者：
DAVIES, L
DAZA, L
GRANGE, P
机构：
[1] Unité de Catalyse et Chimie des Matériaux Divisés, Université Catholique de Louvain, Louvain-la-Neuve, 1348, Place Croix du Sud
来源：
JOURNAL OF MATERIALS SCIENCE | 1995年 / 30卷 / 20期
关键词：
D O I：
10.1007/BF00356053
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Submicrometre particles have been prepared from hydrolysis-polycondensation of zirconium alkoxide [Zr(n-C3H7O)(4)] in ethanolic solution. The properties of these particles (morphology, specific surface area, S-BET, crystal phase and size distribution) after calcination at 450 degrees C for 5 h were found to depend on the conditions of synthesis, i.e. alkoxide concentration and mole ratio water/alkoxide.
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页码：5087 / 5092
页数：6
相关论文
共 25 条
[1]  
BAILEY JK, 1990, MATER RES SOC SYMP P, V180, P153, DOI 10.1557/PROC-180-153
[2]  
BARRETT KEJ, 1975, DISPERSION POLYM ORG, pCH4
[3]   HYDROUS ZIRCONIUM DIOXIDE - INTERFACIAL PROPERTIES, THE FORMATION OF MONODISPERSE SPHERICAL-PARTICLES, AND ITS CRYSTALLIZATION AT HIGH-TEMPERATURES [J].
BLESA, MA ;
MAROTO, AJG ;
PASSAGGIO, SI ;
FIGLIOLIA, NE ;
RIGOTTI, G .
JOURNAL OF MATERIALS SCIENCE, 1985, 20 (12) :4601-4609
[4]   METAL OXIDE ALKOXIDE POLYMERS .1. HYDROLYSIS OF SOME PRIMARY ALKOXIDES OF ZIRCONIUM [J].
BRADLEY, DC ;
CARTER, DG .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1961, 39 (07) :1434-&
[5]   METAL OXIDE ALKOXIDE POLYMERS .3. HYDROLYSIS OF SECONDARY AND TERTIARY ALKOXIDES OF ZIRCONIUM [J].
BRADLEY, DC ;
CARTER, DG .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1962, 40 (01) :15-&
[6]   HYDROLYSIS AND CONDENSATION OF SILICATES - EFFECTS ON STRUCTURE [J].
BRINKER, CJ .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1988, 100 (1-3) :31-50
[7]  
BRINKER CJ, 1990, SOL GEL SCI PHYSICS
[8]  
FEGLEY B, 1985, AM CERAM SOC BULL, V64, P1115
[9]  
Fegley B., 1984, BETTER CERAMICS CHEM, V32, P187
[10]  
FOWKES FM, 1987, ADV CERAM, V21, P411
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