SILVER(I) N-PHTHALOYLGLYCINATE

被引：11

作者：

JABER, F

CHARBONNIER, F

FAURE, R

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270195002447

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, Ag+.C10H6NO4-, was obtained by mixing N-phthaloylglycine and silver nitrate in aqueous solution. The structure is a three-dimensional network based on centrosymmetric eight-membered rings of dimeric [Ag-carboxylato-O,O'](2) units. The Ag polyhedron is a trigonal bipyramid. Each Ag atom is linked to three carboxylic O atoms and one carbonyl O atom belonging to four N-phthaloylglycinate ligands [Ag-O = 2.225(2), 2.228(2), 2.541 (2), 2.612(2) Angstrom], and to another Ag atom [Ag-Ag = 2.8465 (2) Angstrom]. This Ag-Ag interaction in the dimeric unit is short. One of the two carbonyl O atoms of the N-phthaloylglycinate ligand is not involved in the coordination polyhedron.

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页码：1765 / 1767

页数：3

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