N REACTIVITY VS O REACTIVITY IN AQUEOUS CHLORINATION

被引：20

作者：

ARMESTO, XL ^{[1
]}

CANLE, M ^{[1
]}

GARCIA, MV ^{[1
]}

LOSADA, M ^{[1
]}

SANTABALLA, JA ^{[1
]}

机构：

[1] UNIV A CORUNA, FAC CIENCIAS, DEPT QUIM FUNDAMENTAL IND, A ZAPATEIRA S-N, E-15071 LA CORUNA, SPAIN

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1994年 / 26卷 / 11期

关键词：

D O I：

10.1002/kin.550261108

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nitrogenated compounds react with hypochlorous acid yielding N-chloro compounds. In principle, alpha-amino acids chlorination may take place on the oxygen of the carboxylic group or on the nitrogen of the amino group. In this framework, we discuss the different reactivities of nitrogen and oxygen towards chlorine, and come to the conclusion that the nitrogen is the preferred reaction site in alpha-amino acids chlorination. (C) 1994 John Wiley & Sons, Inc.

引用

页码：1135 / 1141

页数：7

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