NONLINEAR-OPTICAL STUDIES OF MOLYBDENUM METAL ORGANICS

被引：4

作者：

ZHAI, T

LAWSON, CM

BURGESS, GE

LEWIS, ML

GALE, DC

GRAY, GM

机构：

[1] UNIV ALABAMA,DEPT MAT SCI,BIRMINGHAM,AL 35294

[2] UNIV ALABAMA,DEPT CHEM,BIRMINGHAM,AL 35294

来源：

OPTICS LETTERS | 1994年 / 19卷 / 12期

关键词：

D O I：

10.1364/OL.19.000871

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

We have measured the third-order susceptibility, chi(3), versus concentration for a number of molybdenum-base metal-organic complexes in solution, using independent degenerate four-wave mixing and Z-scan techniques. Good agreement was obtained between the degenerate four-wave mixing and Z-scan measurements. The variation of chi(3) with concentration yielded the second-order hyperpolarizability gamma. A close correlation was observed between the number of delocalized pi electrons and the magnitude of gamma.

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页码：871 / 873

页数：3

相关论文

共 13 条

[1] PHASE CONJUGATION BY DEGENERATE 4-WAVE MIXING IN ABSORBING MEDIA [J].

CARO, RG ;

GOWER, MC .

IEEE JOURNAL OF QUANTUM ELECTRONICS, 1982, 18 (09) :1376-1380

[2] DYNAMICS OF 3RD-ORDER NONLINEAR OPTICAL PROCESSES IN LANGMUIR-BLODGETT AND EVAPORATED-FILMS OF PHTHALOCYANINES [J].

CASSTEVENS, MK ;

SAMOC, M ;

PFLEGER, J ;

PRASAD, PN .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (03) :2019-2024

[3] A DEGENERATE-4-WAVE-MIXING APPARATUS FOR THE STUDY OF MATERIALS IN SOLUTION [J].

GALE, DC ;

BURGESS, GE ;

ZHAI, T ;

LEWIS, ML .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1993, 64 (11) :3072-3075

[4] OPTICAL NONLINEARITIES OF ORGANOMETALLIC STRUCTURES - ARYL AND VINYL DERIVATIVES OF FERROCENE [J].

GHOSAL, S ;

SAMOC, M ;

PRASAD, PN ;

TUFARIELLO, JJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (07) :2847-2851

[5] REACTIONS OF COORDINATED LIGANDS .6. REACTIONS OF CIS-TETRACARBONYLBIS-(CHLORODIPHENYLPHOSPHINE)MOLYBDENUM(0) WITH AMMONIA, METHYLAMINE, PARA-TOLUIDINE, WATER, METHANOL, PARA-CRESOL, AND ETHANETHIOL AND SUBSEQUENT REACTIONS OF AMMONOLYSIS AND HYDROLYSIS PRODUCTS WITH CHLOROSILANES AND BORON-TRIFLUORIDE DIETHYLETHERATE [J].

GRAY, GM ;

KRAIHANZEL, CS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 146 (01) :23-37

[6]

GROSSMAN C, 1989, NONLINEAR OPTICAL EF, P76

[7]

MCAULIFFE CA, 1979, PHOSPHINE ARSINE STI, pCH5

[8] NONLINEAR TRANSMISSION AND REFLECTION AT A DIELECTRIC CARBON MICROPARTICLE SUSPENSION INTERFACE [J].

MICHAEL, RR ;

LAWSON, CM .

OPTICS LETTERS, 1992, 17 (15) :1055-1057

[9]

PRASAD PN, 1991, INTRO NONLINEAR EFFE, pCH10

[10] SENSITIVE MEASUREMENT OF OPTICAL NONLINEARITIES USING A SINGLE BEAM [J].

SHEIKBAHAE, M ;

SAID, AA ;

WEI, TH ;

HAGAN, DJ ;

VANSTRYLAND, EW .

IEEE JOURNAL OF QUANTUM ELECTRONICS, 1990, 26 (04) :760-769