NONLINEAR-OPTICAL STUDIES OF MOLYBDENUM METAL ORGANICS

被引：4
作者：
ZHAI, T
LAWSON, CM
BURGESS, GE
LEWIS, ML
GALE, DC
GRAY, GM
机构：
[1] UNIV ALABAMA,DEPT MAT SCI,BIRMINGHAM,AL 35294
[2] UNIV ALABAMA,DEPT CHEM,BIRMINGHAM,AL 35294
来源：
OPTICS LETTERS | 1994年 / 19卷 / 12期
关键词：
D O I：
10.1364/OL.19.000871
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
We have measured the third-order susceptibility, chi(3), versus concentration for a number of molybdenum-base metal-organic complexes in solution, using independent degenerate four-wave mixing and Z-scan techniques. Good agreement was obtained between the degenerate four-wave mixing and Z-scan measurements. The variation of chi(3) with concentration yielded the second-order hyperpolarizability gamma. A close correlation was observed between the number of delocalized pi electrons and the magnitude of gamma.
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页码：871 / 873
页数：3
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