AN EFFICIENT PREPARATION OF 6,7-DIDEHYDROESTROGENS

被引：10

作者：

CIATTINI, PG ^{[1
]}

MORERA, E ^{[1
]}

ORTAR, G ^{[1
]}

机构：

[1] UNIV ROMA LA SAPIENZA,CNR,CTR STUDIO CHIM FARMACO,DIPARTIMENTO FARMACEUT,I-00185 ROME,ITALY

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 09期

关键词：

D O I：

10.1080/00397919008052840

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compounds are prepared in excellent yield by palladium-catalyzed reduction with triethyl ammonium formate of enol triflates of 6-oxo-estrogens. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：1293 / 1297

页数：5

共 10 条

[1] AKANNI AO, 1984, SYNTHETIC COMMUN, V14, P713
[2] ARUNACHALAM T, 1979, J BIOL CHEM, V254, P5900
[3] SYNTHESIS OF 3-METHOXYESTRA-1,3,5(10),6-TETRAEN-17-ONE
BROSA, C
FERRER, JC
MALET, C
AMEZAGA, JM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (16) : 3984 - 3985
[4] PALLADIUM-CATALYZED REDUCTION OF ENOL TRIFLATES TO ALKENES
CACCHI, S
MORERA, E
ORTAR, G
[J]. TETRAHEDRON LETTERS, 1984, 25 (42) : 4821 - 4824
[5] STEROIDS .7. CONTRIBUTION TO THE BROMINATION OF DELTA-4-3-KETOSTEROIDS AND A NEW PARTIAL SYNTHESIS OF THE NATURAL ESTROGENS
DJERASSI, C
ROSENKRANZ, G
ROMO, J
KAUFMANN, S
PATAKI, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1950, 72 (10) : 4534 - 4540
[6] IMPROVED PREPARATION OF 3,17-BETA-DIHYDROXYOESTRA-1,3,5(10),6-TETRAENE
GILL, JC
MARPLES, BA
TRAYNOR, JR
[J]. SYNTHETIC COMMUNICATIONS, 1989, 19 (1-2) : 155 - 158
[7] SYNTHESIS OF 3,6-ALPHA,16-ALPHA-TRIHYDROXY-1,3,5(10)-ESTRATRIEN-17-ONE 6-HEMISUCCINATE AND [6,73H]-3,16-ALPHA-DIHYDROXY-1,3,5(10)-ESTRATRIEN-17-ONE
IKEGAWA, S
FISHMAN, J
[J]. STEROIDS, 1982, 39 (05) : 557 - 567
[8] BENZYLIC OXIDATION USING TERT-BUTYL HYDROPEROXIDE IN THE PRESENCE OF CHROMIUM HEXACARBONYL
PEARSON, AJ
HAN, GR
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (15) : 2791 - 2792
[9] PHOTOCHEMICAL-REACTIONS .23. PHOTO-OXYGENATION OF STYRENIC ESTROGENS - PRODUCT CHARACTERIZATION AND KINETICS OF THE DYE-SENSITIZED PHOTO-OXYGENATION OF 9,11-DIDEHYDROESTRONE DERIVATIVES
PLANAS, A
LUPON, P
CASCALLO, M
BONET, JJ
[J]. HELVETICA CHIMICA ACTA, 1989, 72 (04) : 715 - 724
[10] SYNTHESIS OF 11-OXAESTROGENS VIA DYE-SENSITIZED PHOTO-OXYGENATION OF A 9,11-DIDEHYDROESTRONE DERIVATIVE
PLANAS, A
SALA, N
BONET, JJ
[J]. HELVETICA CHIMICA ACTA, 1989, 72 (04) : 725 - 730

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