AN INTRAMOLECULARLY LEWIS-BASE-STABILIZED GE=N-COMPOUND AND A RELATED GE-FE COMPLEX

被引：79

作者：

VEITH, M

BECKER, S

HUCH, V

机构：

[1] Institut für Anorganische Chemie, Universität Saarbrücken

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 02期

关键词：

D O I：

10.1002/anie.199002161

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Exclusively nitrogen atoms constitute the co‐ordination sphere of germanium in 1. The NGe donor bond fluctuates, as observed for the analogous GeS compound 2. In the analogous iron complex 3, on the other hand, it is static on the NMR time scale, at least up to 90°C. Whereas a GeFe single bond is present in 3, partial GeN double‐bond character is found for 1. Furthermore, a zwitter‐ionic resonance structure must be considered in describing 1. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：216 / 218

页数：3

共 11 条

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