1,3-DICHALCOGENA-2-VANADA-[3]FERROCENOPHANES

被引：26

作者：

HERBERHOLD, M ^{[1
]}

SCHREPFERMANN, M ^{[1
]}

RHEINGOLD, AL ^{[1
]}

机构：

[1] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 394卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(90)87228-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the half-sandwich compounds CpV(O)Cl2 (2a) and Cp {black star}V(O)Cl2 (2b) with dilithio-1,1′-ferrocene dichalcogenates have been used to prepare bimetallic complexes [Fe(C5H4E)2]V(O)Cp (E = S (3a), Se (4a)) and [Fe(C5H4E)2]V(O)Cp{black star} (E = S (3b), Se (4b)). An X-ray diffraction study of 4b confirms the absence of bonding interactions between the metal centres (Fe ··· V 401.4(2) pm). © 1990.

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页码：113 / 120

页数：8

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