A Single-Stage Catalytic Process for Obtaining Dimethyl Ether from Synthesis Gas

被引:0
作者
Kosova, N. I. [1 ]
Kurina, L. N. [1 ]
机构
[1] Tomsk State Univ, Pr Lenina 36, Tomsk 634050, Russia
来源
CHEMISTRY FOR SUSTAINABLE DEVELOPMENT | 2011年 / 19卷 / 02期
关键词
synthesis gas; CuO/ZnO/Al2O3; catalyst; dimethyl ether;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Obtaining dimethyl ether from synthesis gas with the use of a two-layer catalyst was studied. An optimum level-by-level loading was determined for two catalytic systems such as methanol production catalyst Katalco-58 and methanol dehydration catalyst gamma-Al2O3. It was demonstrated that increasing the temperature and contact time results in increasing the CO conversion level and the yield of dimethyl ether, whereas their maximum values are attained at a pressure of 3 MPa. The optimum process conditions are: T = 280 degrees C, P = 3 MPa, H-2/CO = 2, the contact time 6 s.
引用
收藏
页码:201 / 205
页数:5
相关论文
共 7 条
[1]   The potential of di-methyl ether (DME) as an alternative fuel for compression-ignition engines: A review [J].
Arcoumanis, Constantine ;
Bae, Choongsik ;
Crookes, Roy ;
Kinoshita, Eiji .
FUEL, 2008, 87 (07) :1014-1030
[2]   Direct synthesis of dimethyl ether from (H2+CO) and (H2+CO2) feeds.: Effect of feed composition [J].
Ereña, J ;
Garoña, R ;
Arandes, JM ;
Aguayo, AT ;
Bilbao, J .
INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING, 2005, 3
[3]   Synthesis of gasoline from syngas via dimethyl ether [J].
Kolesnichenko, N. V. ;
Kitaev, L. E. ;
Bukina, Z. M. ;
Markova, N. A. ;
Yushchenko, V. V. ;
Yashina, O. V. ;
Lin, G. I. ;
Rozovskii, A. Ya. .
KINETICS AND CATALYSIS, 2007, 48 (06) :789-793
[4]  
KUZNETSOV VD, 1982, KINET KATAL, V23, P932
[5]  
Popova N. M., 2007, KATALIZATORY SELEKTI
[6]  
Rozovskiy A.YA., 1990, TEORETICHESKIYE OSNO
[7]  
[No title captured]