NONLINEAR-OPTICAL PROPERTIES OF TRANSITION METAL-PHOSPHINE COMPLEXES

被引：32

作者：

ZHAI, T

LAWSON, CM

GALE, DC

GRAY, GM

机构：

[1] UNIV ALABAMA,DEPT MAT SCI,BIRMINGHAM,AL 35294

[2] UNIV ALABAMA,DEPT CHEM,BIRMINGHAM,AL 35294

来源：

OPTICAL MATERIALS | 1995年 / 4卷 / 04期

关键词：

D O I：

10.1016/0925-3467(94)00126-X

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Nonlinear optical properties of transition metal-phosphine complexes have been measured at 532 nm by degenerate four-wave mixing. Large nonresonant second-order molecular hyperpolarizabilities, gamma, have been found for complexes containing two phosphine ligands. The measured gamma values are closely related to the type and coordination geometry of the phosphine ligands. A numerical fitting of gamma values versus the number of substituents with pi-electrons on the ligand gives a result similar to what is observed for linear conjugated oligomers.

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页码：455 / 460

页数：6

相关论文

共 28 条

[1]

AGNAWAL GP, 1978, PHYS REV B, V17, P776

[2] 3RD-ORDER NONLINEAR-OPTICAL RESPONSE IN ORGANIC MATERIALS - THEORETICAL AND EXPERIMENTAL ASPECTS [J].

BREDAS, JL ;

ADANT, C ;

TACKX, P ;

PERSOONS, A ;

PIERCE, BM .

CHEMICAL REVIEWS, 1994, 94 (01) :243-278

[3]

BURGESS GE, 1993, THESIS U ALABAMA BIR

[4] PHASE CONJUGATION BY DEGENERATE 4-WAVE MIXING IN ABSORBING MEDIA [J].

CARO, RG ;

GOWER, MC .

IEEE JOURNAL OF QUANTUM ELECTRONICS, 1982, 18 (09) :1376-1380

[5] DYNAMICS OF 3RD-ORDER NONLINEAR OPTICAL PROCESSES IN LANGMUIR-BLODGETT AND EVAPORATED-FILMS OF PHTHALOCYANINES [J].

CASSTEVENS, MK ;

SAMOC, M ;

PFLEGER, J ;

PRASAD, PN .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (03) :2019-2024

[6]

CHEMLA DS, 1986, NONLINEAR OPTICS MAT

[7]

ELSCHENBROICH C, 1992, ORGANOMETALLICS CONC, pCH12

[8] A DEGENERATE-4-WAVE-MIXING APPARATUS FOR THE STUDY OF MATERIALS IN SOLUTION [J].

GALE, DC ;

BURGESS, GE ;

ZHAI, T ;

LEWIS, ML .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1993, 64 (11) :3072-3075

[9] OPTICAL NONLINEARITIES OF ORGANOMETALLIC STRUCTURES - ARYL AND VINYL DERIVATIVES OF FERROCENE [J].

GHOSAL, S ;

SAMOC, M ;

PRASAD, PN ;

TUFARIELLO, JJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (07) :2847-2851

[10] REACTIONS OF COORDINATED LIGANDS .6. REACTIONS OF CIS-TETRACARBONYLBIS-(CHLORODIPHENYLPHOSPHINE)MOLYBDENUM(0) WITH AMMONIA, METHYLAMINE, PARA-TOLUIDINE, WATER, METHANOL, PARA-CRESOL, AND ETHANETHIOL AND SUBSEQUENT REACTIONS OF AMMONOLYSIS AND HYDROLYSIS PRODUCTS WITH CHLOROSILANES AND BORON-TRIFLUORIDE DIETHYLETHERATE [J].

GRAY, GM ;

KRAIHANZEL, CS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 146 (01) :23-37