CONCERNING THE ASYMMETRIC METALATION OF FERROCENES BY CHIRAL LITHIUM AMIDE BASES

被引：81
作者：
PRICE, D [1 ]
SIMPKINS, NS [1 ]
机构：
[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 34期
关键词：
D O I：
10.1016/0040-4039(95)01161-A
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The asymmetric metallation of diphenylphosphinyl ferrocene 5h, to give the silyl substituted product 6h was accomplished in 95% yield and 54% ee using the chiral lithium amide base 2: attempts to extend this reaction to other ferrocenes were unsuccessful.
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页码：6135 / 6136
页数：2
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