NEW EVIDENCE OF THE PROMOTION OF ACTIVITY AND SELECTIVITY THROUGH HYDROGEN SPILL-OVER ACTIVATION OF BIPHASIC SULFIDED HYDROTREATING CATALYSTS

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作者
DELEON, SG
GRANGE, P
DELMON, B
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Bulk MoS2 (or WS2) were mechanically mixed with noble metal supported phases (PtS/gamma-Al2O3; Rh2S3/gamma-Al2O3 and PdS/gamma-Al2O3. Using these non conventional hydrotreating catalysts, we showed that both, hydrodesulfurization (HDS) of thiophene and hydrogenation (HYD) of cyclohexene, activities were increased. In all the range of composition of the mixed solids a synergy was obtained.
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页码:345 / 348
页数:4
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