SYNTHESIS AND X-RAY STRUCTURE OF THE DIVALENT AND TRIVALENT YTTERBIUM-MOLYBDENUM COMPLEXES YB(II)(HMPA)4(MU-OCMO(CO)2CP)2 AND [YB(III)(HMPA)5(MU-OCMO(CO)2CP)][CPMO(CO)3]2-CENTER-DOT-THF

被引：0

作者：

HOU, ZM ^{[1
]}

AIDA, K ^{[1
]}

TAKAGI, Y ^{[1
]}

WAKATSUKI, Y ^{[1
]}

机构：

[1] NIHON UNIV,COLL HUMANITIES & SCI,DEPT CHEM,SETAGAYA KU,TOKYO 156,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 473卷 / 1-2期

关键词：

YTTERBIUM; MOLYBDENUM; CARBONYL; KETONE DIANION; X-RAY DIFFRACTION; CRYSTAL STRUCTURE;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the ytterbium-benzophenone dianion complex [YbII(mu-OCPh2)(HMPA)2]2 with two molar equivalents of CpMo(CO)3H in THF/ HMPA (THF = tetrahydrofuran, HMPA = hexamethylphosphoramide) gave a divalent ytterbium-molybdenum complex YbII(HMPA)4(mu-OCMo(CO)2CP)2 (1) in which the two molybdenumcarbonylate units are coordinated to Yb(II) in cisoid orientation. When four equivalents Of CPMO(CO)3H were used, the trivalent ytterbium-molybdenum complex [YbIII(HMPA)5(mu-OCMo(CO)2CP)][CPMo(CO)3]2. THF (2) was formed. Both 1 and 2 were structurally characterized by X-ray crystallography.

引用

页码：101 / 104

页数：4

共 38 条

[1] Mixed-metal cluster chemistry .5. Syntheses and x-ray crystal structure of Cp2Mo2Ir2(mu(3)-CO)(mu-CO)(5)(CO)(4)
Lucas, NT
Humphrey, MG
Hockless, DCR
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 535 (1-2) : 175 - 181
[2] Reactions of SmI2(THF)(x) with [Cp'Mo(CO)(3)]Hg-2(Cp'=C5H5- or C(5)Me(5)(-)): Crystal and molecular structures of [(THF)(4)I2Sm(mu-OC)Mo(CO)(2)(C5H5)] and [(C(5)Me(5))Mo(CO)(3)](2)
Lin, GY
Wong, WT
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 522 (02) : 271 - 275
[3] [Na(THF)2(μ2-η5-Cp)(η5,η5,η1-Cp3Yb)(THF)]n:: The synthesis and X-ray structure of an anionic organolanthanide polymer formed via self-assembly
Huang, D
Sun, HM
Liu, TQ
Xu, F
Shen, Q
CHINESE SCIENCE BULLETIN, 2005, 50 (17): : 1843 - 1845
[4] [Na(THF)2(μ2-η~5-Cp)(η~5,η~5,η~1- Cp3Yb)(THF)]n:The synthesis and X-ray structure of an anionic organolanthanide polymer formed via self-assembly
HUANG Dan
ChineseScienceBulletin, 2005, (17) : 29 - 31
[5] 2,5-DIMETHYLTHIOPHENE COORDINATION TO 3 METAL CENTERS IN THE COMPLEXES (MU-4,S-MU-3-2,5-ME2T)(IRCP-ASTERISK) [M(CO)2CP]2 WHERE M = MO OR W
CHEN, J
ANGELICI, RJ
APPLIED ORGANOMETALLIC CHEMISTRY, 1992, 6 (05) : 479 - 487
[6] Reactions of Ru-5(mu(5)-C(2)PPh(2))(mu-PPh(2))(CO)(13) with functional phosphines. X-ray structures of Ru-5(mu(5)-C(2)PPh(2))(mu-PPh(2))(dppm)(CO)(12)center dot CHCl3 Ru-5(mu(5)-C2H)(mu-PPh(2))(2)(mu-P,N-PPh(2)C(6)H(4)NH-2)(mu-CO)(CO)(10), Ru-4{mu(4)-C(2)PPh(2)[Ru(mu-OH)(C, P-2-CHMeC(6)H(4)PPh(2)-2)(CO)(2)]}-(mu-PPh(2))(CO)(10)center dot CHCl3 and Ru-5(mu-H)(2){mu(5)-PPh(2)C(2)CHC(C(6)H(4)PPh(2)-2)}(mu-PPh(2))(CO)(11)
Adams, CJ
Bruce, MI
Skelton, BW
White, AH
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 513 (1-2) : 255 - 271
[7] Organometallic compounds of the lanthanoids .3. Synthesis and characterization of cationic metallocene complexes of the lanthanoides. X-ray crystal structure of [Cp(2)(*)Yb(THF)(2)][BPh(4)]
Schumann, H
Winterfeld, J
Keitsch, MR
Herrmann, K
Demtschuk, J
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (09): : 1457 - 1461
[8] Synthesis and X-ray crystal structures of phosphido-bridged heterobimetallic complexes: [FeIr(mu-CO)(CO)(4)(mu-P(t)Bu(2))((t)Bu(2)PH)] and [CoIr(CO)(5)(mu-H)(mu-P(t)Bu(2))((t)Bu(2)PH)]
Bottcher, HC
Graf, M
Merzweiler, K
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 525 (1-2) : 191 - 197
[9] Solvo-Thermal Application for the Synthesis of [Et4N][(mu-H)Mo-2(CO)(10)] and its Bidentate Phosphine Derivatives and the X-ray Structure of (mu-Ph2P(CH2)(2)PPh2) [Mo (CO)(4)(NCCH3)]
El-mehdawi, R. M.
Darensbourg, M. Y.
Eldewik, N. A.
Trish, F. A.
Ben Younes, M. M.
JORDAN JOURNAL OF CHEMISTRY, 2009, 4 (03) : 243 - 250
[10] SYNTHESIS OF TRINUCLEAR CARBONYLMANGANATES AND THEIR REACTION-PRODUCTS WITH INCL3 - X-RAY STRUCTURE DETERMINATIONS OF K3[MN3(MU-CO)2(CO)10], [(C6H5)4AS]2[(MU-H)MN3(MU-CO)2(CO)10], [((C6H5)3P)2N]2[(MU-H)MN3(CO)12], [(C6H5)4AS]2[((MU-H)-MN3(CO)12)2(MU-4-IN)], AND [(C6H5)4AS]2[((MU-H)MN3(CO)12)(MU-3-IN)(MN(CO)5)CL]
SCHATZ, W
NEUMANN, HP
NUBER, B
KANELLAKOPULOS, B
ZIEGLER, ML
CHEMISCHE BERICHTE, 1991, 124 (03) : 453 - 463

← 1 2 3 4 →