ANALYTICAL-CHEMISTRY OF POLYTHIONATES AND THIOSULFATE - A REVIEW

被引：42
作者：
KOH, T [1 ]
机构：
[1] TOKAI UNIV,FAC SCI,DEPT CHEM,HIRATSUKA,KANAGAWA 25912,JAPAN
来源：
ANALYTICAL SCIENCES | 1990年 / 6卷 / 01期
关键词：
polythionates high performance liquid chromatography; polythionates mixture analysis; polythionates reaction; spectrophotometry; Wackenroder's solution;
D O I：
10.2116/analsci.6.3
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The reaction of hydrogen sulfide with sulfur dioxide in aqueous solution yields Wackenroder's solution, which contains polythionates (SxO62-: x=3, 4 and 5) and thiosulfate. Various reactions of polythionates with such reagents as sulfite, cyanide, sulfide, permanganate and others are reviewed, in which the thiosulfate and/or thiocyanate formed by these reactions of polythionates are measured titrimetrically, spectrophotometrically and coulometrically. As a result, simultaneous equations can be obtained through corresponding different procedures and can be used for the determination of polythionates in their mixtures with other sulfur anions. Furthermore, modern liquid chromatography is described for the separation of polythionates and thiosulfate, in which quite different chromatographic techniques and conditions were employed. © 1990, The Japan Society for Analytical Chemistry. All rights reserved.
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页码：3 / 14
页数：12
相关论文
共 76 条
[1]   APPLICATION OF AMPEROMETRIC DEAD STOP END POINT TO IODATE PROCEDURES IN PRESENCE OF MERCURIC MERCURY [J].
BAPAT, MG ;
SHARMA, B .
FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1957, 157 (04) :258-261
[2]   SEPARATION AND DETERMINATION OF MIXTURES OF POLYTHIONATES [J].
BLASIUS, E ;
MUNCH, J .
FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1974, 272 (05) :346-353
[3]   RAPID COULOMETRIC MICRODETERMINATION OF INDIVIDUAL POLYTHIONATES [J].
BLASIUS, E ;
MUNCH, J .
FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1972, 261 (03) :198-&
[4]   FAST ANALYTICAL PROCEDURE FOR SEPARATION AND DETERMINATION OF POLYTHIONATES FOUND IN WACKENRODERS SOLUTION BY HIGH-SPEED LIQUID CHROMATOGRAPHY [J].
CHAPMAN, JN ;
BEARD, HR .
ANALYTICAL CHEMISTRY, 1973, 45 (13) :2268-2270
[5]  
FOGO DN, 1952, J APPL CHEM, V2, P357
[6]   POLAROGRAPHY OF THE TETRATHIONATE ION [J].
FURNESS, W ;
DAVIES, WC .
ANALYST, 1952, 77 (920) :697-707
[7]   *QUANTITATIVE BESTIMMUNG DER POLYTHIONATE (TRITHIONAT, TETRATHIONAT, PENTATHIONAT UND HEXATHIONAT) NEBENEINANDER [J].
GOEHRING, M ;
FELDMANN, U ;
HELBING, W .
FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1949, 129 (4-5) :346-352
[8]   UEBER DIE SULFOXYLSAURE .3. DIE SPONTANE ZERSETZUNG VON POLYTHIONATLOSUNGEN [J].
GOEHRING, M ;
HELBING, W ;
APPEL, I .
ZEITSCHRIFT FUR ANORGANISCHE CHEMIE, 1947, 254 (3-4) :185-200
[9]  
GOTO H, 1944, NIPPON KAGAKU KAISHI, V65, P673
[10]  
HAFF LV, 1970, ANAL CHEM SULFUR ITS, P238
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