FLASH-PHOTOLYTIC GENERATION OF ACETOPHENONE ENOL - THE KETO ENOL EQUILIBRIUM-CONSTANT AND PKA OF ACETOPHENONE IN AQUEOUS-SOLUTION

被引：102
作者：
CHIANG, Y
KRESGE, AJ
WIRZ, J
机构：
[1] UNIV TORONTO,SCARBOROUGH COLL,DEPT CHEM,W HILL M1C 1A4,ONTARIO,CANADA
[2] UNIV BASEL,INST PHYS CHEM,CH-4056 BASEL,SWITZERLAND
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1984年 / 106卷 / 21期
关键词：
D O I：
10.1021/ja00333a049
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
引用
收藏
页码：6392 / 6395
页数：4
相关论文
共 37 条
[1]  
ALBERY WJ, 1975, PROTON TRANSFER REAC, P289
[2]  
AURELLY M, 1980, B SOC CHIM FR II-CH, P385
[3]  
BATES RG, 1973, DETERMINATION PH THE, P49
[4]   Rates and equilibria in the ionisation of C-H bonds. [J].
Bell, RP .
TRANSACTIONS OF THE FARADAY SOCIETY, 1943, 39 :0253-0259
[5]   ALKYL EFFECTS ON EQUILIBRIUM ACIDITIES OF CARBON ACIDS IN PROTIC AND DIPOLAR APROTIC MEDIA AND IN GAS-PHASE [J].
BORDWELL, FG ;
BARTMESS, JE ;
HAUTALA, JA .
JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (16) :3095-3101
[6]   SIMPLE ENOLS .2. KINETICS AND MECHANISM OF THE KETONIZATION OF VINYL ALCOHOL [J].
CAPON, B ;
ZUCCO, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (26) :7567-7572
[7]   KETONIZATION OF ENOLS - ENOL CONTENT AND ACID DISSOCIATION-CONSTANTS OF SIMPLE CARBONYL-COMPOUNDS [J].
CHIANG, Y ;
KRESGE, AJ ;
WALSH, PA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (22) :6122-6123
[8]   PKA AND KETO-ENOL EQUILIBRIUM-CONSTANT OF ACETONE IN AQUEOUS-SOLUTION [J].
CHIANG, Y ;
KRESGE, AJ ;
TANG, YS ;
WIRZ, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (02) :460-462
[9]   KINETIC-EQUATIONS FOR REACTIONS IN CONCENTRATED AQUEOUS ACIDS BASED ON THE CONCEPT OF EXCESS ACIDITY [J].
COX, RA ;
YATES, K .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1979, 57 (22) :2944-2951
[10]   THE EXCESS ACIDITY OF AQUEOUS HCL AND HBR MEDIA - AN IMPROVED METHOD FOR THE CALCULATION OF X-FUNCTIONS AND H0 SCALES [J].
COX, RA ;
YATES, K .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1981, 59 (14) :2116-2124
1234