AN ABINITIO MOLECULAR-ORBITAL STUDY OF THE 2-ADAMANTYL CATION

被引：49

作者：

DUTLER, R ^{[1
]}

RAUK, A ^{[1
]}

SORENSEN, TS ^{[1
]}

WHITWORTH, SM ^{[1
]}

机构：

[1] UNIV CALGARY, DEPT CHEM, CALGARY T2N 1N4, ALBERTA, CANADA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1989年 / 111卷 / 25期

关键词：

D O I：

10.1021/ja00207a006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：9024 / 9029

页数：6

共 86 条

[1]

ANDO T, 1977, TETRAHEDRON LETT, P2775

[2]

[Anonymous], 1977, J AM CHEM SOC

[3] NUCLEOPHILIC DISPLACEMENTS AT 4,4-DIMETHYL-2-ADAMANTYL SUBSTRATES - BACKSIDE ATTACK ON 2-ADAMANTYL DERIVATIVES [J].

BANERT, K ;

KURNIANTO, A .

CHEMISCHE BERICHTE-RECUEIL, 1986, 119 (12) :3826-3841

[4]

BANERT K, 1986, RECL TRAV CHIM PAY B, V105, P272

[5] RELATIVELY FAST SOLVOLYTIC REACTIONS OF 1-ADAMANTYL MESYLATE - FURTHER DEVELOPMENT OF THE YOTS SCALE OF SOLVENT IONIZING POWER AND THE NOTS SCALE OF SOLVENT NUCLEOPHILICITY [J].

BENTLEY, TW ;

CARTER, GE .

JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (04) :579-584

[6] SN2 CHARACTER OF SOLVOLYSES OF TERT-BUTYL HALIDES AND OF TRIFLUOROACETOLYSES OF SECONDARY ALKYL SULFONATES [J].

BENTLEY, TW ;

BOWEN, CT ;

PARKER, W ;

WATT, CIF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (09) :2486-2488

[7] THE SN2-SN1 SPECTRUM .3. SOLVOLYSES OF SECONDARY AND TERTIARY ALKYL SULFONATES IN FLUORINATED ALCOHOLS - FURTHER EVIDENCE FOR THE SN2 (INTERMEDIATE) MECHANISM [J].

BENTLEY, TW ;

BOWEN, CT ;

MORTEN, DH ;

SCHLEYER, PV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (18) :5466-5475

[8] EVIDENCE AGAINST APPRECIABLE INTERNAL ION-PAIR RETURN IN THE SOLVOLYSES OF TERTIARY ALIPHATIC HALIDES - MEASUREMENT OF ALPHA-METHYL-HYDROGEN RATE RATIOS IN HEXAFLUOROPROPAN-2-OL-WATER [J].

BENTLEY, TW ;

BOWEN, CT ;

PARKER, W ;

WATT, CIF .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1980, (08) :1244-1252

[9] SOLVOLYSES OF SECONDARY SULFONATES IN AQUEOUS ETHANOL AND ACETONE - NON-LINEAR MY RELATIONSHIPS DUE TO LEAVING GROUP AND MEDIUM EFFECTS [J].

BENTLEY, TW ;

BOWEN, CT ;

BROWN, HC ;

CHLOUPEK, FJ .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (01) :38-42

[10] HYDROLYSIS OF SECONDARY ALKYL SULFONATES - SN2 REACTIONS WITH HIGH CARBOCATION CHARACTER [J].

BENTLEY, TW ;

BOWEN, CT .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1978, (06) :557-562

← 1 2 3 4 5 6 7 8 9 →