GLYCOSIDES FROM ASTER YUNNANENSIS

被引:15
作者
SHAO, Y
ZHOU, BN
GAO, JH
LIN, LZ
CORDELL, GA
机构
[1] ACAD SINICA,SHANGHAI INST MAT MED,SHANGHAI 200031,PEOPLES R CHINA
[2] UNIV ILLINOIS,COLL PHARM,PROGRAM COLLABORAT RES PHARMACEUT SCI,CHICAGO,IL 60612
关键词
ASTER YUNNANENSIS; COMPOSITAE; TRITERPENE SAPONINS; ACETYLENE GLYCOSIDE; BAYOGENIN; ASTERYUNNANOSIDE E AND I;
D O I
10.1016/0031-9422(94)00716-7
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A new oleanane-type triterpene saponin named asteryunnanoside E and a new acetylene glycoside named asteryunnanoside I have been isolated from the roots of Aster yunnanensis, and their structures elucidated as 3-O-beta-D-glucopyranosyl-bayogenin-28-O-beta-D-glucopyranosyl-(1 --> 2)-beta-D-glucopyranoside and 2Z,8E-decadiene-4,6-diyn-1-O-beta-D-glucopyranosyl-(1 --> 2)-beta-D-glucopyranoside by means of 1D and 2D NMR techniques (COSY, HETCOR, COLOC, HOHAHA and ROESY) and chemical transformations.
引用
收藏
页码:675 / 680
页数:6
相关论文
共 11 条
[1]   PLANTS OF MOZAMBIQUE .7. TRITERPENOIDS OF TERMINALIA-SERICEA [J].
BOMBARDELLI, E ;
BONATI, A ;
GABETTA, B ;
MUSTICH, G .
PHYTOCHEMISTRY, 1974, 13 (11) :2559-2562
[2]   STRUCTURE DETERMINATION OF A TETRASACCHARIDE - TRANSIENT NUCLEAR OVERHAUSER EFFECTS IN THE ROTATING FRAME [J].
BOTHNERBY, AA ;
STEPHENS, RL ;
LEE, JM ;
WARREN, CD ;
JEANLOZ, RW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (03) :811-813
[3]   COHERENCE TRANSFER BY ISOTROPIC MIXING - APPLICATION TO PROTON CORRELATION SPECTROSCOPY [J].
BRAUNSCHWEILER, L ;
ERNST, RR .
JOURNAL OF MAGNETIC RESONANCE, 1983, 53 (03) :521-528
[4]  
DAVIS DG, 1985, J AM CHEM SOC, V107, P2821
[5]   FREQUENCY OFFSET EFFECTS AND THEIR ELIMINATION IN NMR ROTATING-FRAME CROSS-RELAXATION SPECTROSCOPY [J].
GRIESINGER, C ;
ERNST, RR .
JOURNAL OF MAGNETIC RESONANCE, 1987, 75 (02) :261-271
[6]   SAPONINS FROM BOLBOSTEMMA-PANICULATUM - CYCLIC BISDESMOSIDES, TUBEIMOSIDE-II AND TUBEIMOSIDE-III [J].
KASAI, R ;
MIYAKOSHI, M ;
NIE, RL ;
ZHOU, J ;
MATSUMOTO, K ;
MORITA, T ;
NISHI, M ;
MIYAHARA, K ;
TANAKA, O .
PHYTOCHEMISTRY, 1988, 27 (05) :1439-1446
[7]   ASSIGNMENT OF CARBONYL CARBONS AND SEQUENCE-ANALYSIS IN PEPTIDES BY HETERONUCLEAR SHIFT CORRELATION VIA SMALL COUPLING-CONSTANTS WITH BROAD-BAND DECOUPLING IN T1 (COLOC) [J].
KESSLER, H ;
GRIESINGER, C ;
ZARBOCK, J ;
LOOSLI, HR .
JOURNAL OF MAGNETIC RESONANCE, 1984, 57 (02) :331-336
[8]   SELECTIVE CLEAVAGE OF ESTER TYPE GLYCOSIDE-LINKAGES AND ITS APPLICATION TO STRUCTURE DETERMINATION OF NATURAL OLIGOGLYCOSIDES [J].
OHTANI, K ;
MIZUTANI, K ;
KASAI, R ;
TANAKA, O .
TETRAHEDRON LETTERS, 1984, 25 (40) :4537-4540
[9]  
SHAO Y, 1995, IN PRESS PHYTOCHEMIS
[10]  
SOE S, 1978, J AM CHEM SOC, V100, P3331