A NEW OPERATING MODE OF A QUADRUPOLE ION-TRAP IN MASS-SPECTROMETRY .1. SIGNAL VISIBILITY

被引：8
|
作者：
ZEREGA, Y
ANDRE, J
BRINCOURT, G
CATELLA, R
机构：
[1] Laboratoire de Physique des Interactions Ioniques et Moléculaires, (Unité de Recherche Associée au C.N.R.S. no 773), Université de Provence, F 13397 Marseille Cedex20
来源：
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES | 1994年 / 132卷 / 1-2期
关键词：
ION TRAP; FOURIER TRANSFORM; SIGNAL VISIBILITY;
D O I：
10.1016/0168-1176(94)85019-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
We explain a new operating mode of a quadrupole ion trap in mass spectrometry using a Fourier transform technique without additional excitation of ion motion. We introduce a mathematical formalism to describe the operating mode. Theoretical calculations are made to show the shape of the spectrum. We give an estimation of the signal-to-noise ratio with a single ion species at the secular frequency. In the case of two ion species, we notice the influence of the most abundant species over the other. Experimental results confirm the theoretical predictions and show the very good sensitivity of this method, even with few confined ions.
引用
收藏
页码：57 / 65
页数：9
相关论文
共 39 条
  • [31] Qualitative Analysis of the Major Constituents in Traditional Oriental Prescription Bang-poong-tong-sung-san by Liquid Chromatography/Ultraviolet Detector/Ion-Trap Time-of-Flight Mass Spectrometry
    Eom, Han Young
    Kim, Hyung-Seung
    Han, Sang Beom
    MASS SPECTROMETRY LETTERS, 2014, 5 (01) : 24 - 29
  • [32] Automated software-guided identification of new buspirone metabolites using capillary LC coupled to ion trap and TOF mass spectrometry
    Fandiño, AS
    Nägele, E
    Perkins, PD
    JOURNAL OF MASS SPECTROMETRY, 2006, 41 (02): : 248 - 255
  • [33] De novo sequencing of a 21-kDa cytochrome c4 from Thiocapsa roseopersicina by nanoelectrospray ionization ion-trap and Fourier-transform icon-cyclotron resonance mass spectrometry
    Branca, Rlii Miguel Marnede
    Bodo, Gabriella
    Bagyinka, Csaba
    Prokai, Laszlo
    JOURNAL OF MASS SPECTROMETRY, 2007, 42 (12): : 1569 - 1582
  • [34] New variants of polar glycopeptidolipids detected in Mycobacterium simiae, including 'habana' strains, as evidenced by electrospray ionization-ion trap-mass spectrometry
    Mederos, L.
    Valdivia, J. A.
    Valero-Guillen, P. L.
    JOURNAL OF APPLIED MICROBIOLOGY, 2008, 105 (02) : 602 - 614
  • [35] A comprehensive library-based, automated screening procedure for 46 synthetic cannabinoids in serum employing liquid chromatography-quadrupole ion trap mass spectrometry with high-temperature electrospray ionization
    Huppertz, Laura M.
    Kneisel, Stefan
    Auwaerter, Volker
    Kempf, Juergen
    JOURNAL OF MASS SPECTROMETRY, 2014, 49 (02): : 117 - 127
  • [36] Comparison of the structures of triacylglycerols from native and transgenic medium-chain fatty acid-enriched rape seed oil by liquid chromatography-atmospheric pressure chemical ionization ion-trap mass spectrometry (LC-APCI-ITMS)
    Beermann, Christopher
    Winterling, Nadine
    Green, Angelika
    Moebius, Michael
    Schmitt, Joachim J.
    Boehm, Guenther
    LIPIDS, 2007, 42 (04) : 383 - 394
  • [37] Separation and Characterization of New Components and Impurities in Leucomycin by Multiple Heart-Cutting Two-Dimensional Liquid Chromatography Combined with Ion Trap/Time-of-Flight Mass Spectrometry
    Wang, Jian
    Liu, Guijun
    Xu, Yu
    Zhu, Bingqi
    Wang, Zhijian
    CHROMATOGRAPHIA, 2019, 82 (09) : 1333 - 1344
  • [38] Characterization of Ni(II) complexes of Schiff bases of amino acids and (S)-N-(2-benzoylphenyl)-1-benzylpyrrolidine-2-carboxamide using ion trap and QqTOF electrospray ionization tandem mass spectrometry
    Jirasko, Robert
    Holcapek, Michal
    Kolarova, Lenka
    Nadvornik, Milan
    Popkov, Alexander
    JOURNAL OF MASS SPECTROMETRY, 2008, 43 (09): : 1274 - 1284
  • [39] Hb Neuilly-sur-Marne, a new human hemoglobin variant with Ser-Asp-Leu inserted between α86(F7) Leu and α87(F8) His:: characterization by high-energy collision-induced dissociation liquid secondary ion mass spectrometry and low energy collision-induced dissociation tandem mass spectrometry in an ion trap fitted with a nanospray ionization source
    Promé, D
    Promé, JC
    Wajcman, H
    Riou, J
    Galactéros, F
    Carte, N
    Leize, E
    Vandorsselaer, A
    EUROPEAN JOURNAL OF MASS SPECTROMETRY, 2000, 6 (02) : 205 - 211
1234