SYNTHESIS, MOLECULAR-STRUCTURE AND NMR BEHAVIOR OF [9,9-(PME2PH)2-ARACHNO-9,6,8-PTS2B7H7] - DIRECT EVIDENCE FOR THE 10-VERTEX BORANE VERTEX-FLIP MECHANISM OF ISOMERIZATION

被引：23

作者：

JONES, JH

FONTAINE, XLR

GREENWOOD, NN

KENNEDY, JD

THORNTONPETT, M

STIBR, B

LANGHOFF, H

机构：

[1] UNIV LEEDS, SCH CHEM, LEEDS LS2 9JT, W YORKSHIRE, ENGLAND

[2] CZECHOSLOVAK ACAD SCI, INST INORGAN CHEM, CS-25068 REZ, CZECHOSLOVAKIA

[3] STOE & CIE GMBH, W-6100 DARMSTADT, GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 445卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80225-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ten-vertex cluster compound [9,9-(PMe2Ph)2-arachno-9,6,8-PtS2B7H7] is fluxional between its two enantiomers via a vertex-flip of the {Pt(PMe2Ph)2} group between the eta3-10,4,8 and eta3-10,5,6 positions of the formal nine-vertex arachno-shaped {S2B7H7} ligand moiety.

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页码：C15 / C16

页数：2

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