Trichlorido(6-methyl-2,2 '-bipyridinej kappa N-2,N ')(dimethylsulfoxide-kappa O)indium(III)

被引：1

作者：

Shirvan, Sadif A. ^{[1
]}

Dezfuli, Sara Haydari ^{[1
]}

Golabi, Elyas ^{[2
]}

Gholamzadeh, Mohammad Amin ^{[2
]}

机构：

[1] IslamicAzad Univ, Dept Chem, Omidieh Branch, Omidieh, Iran

[2] IslamicAzad Univ, Dept Petr Engn, Omidieh Branch, Omidieh, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 18.2; mean ̄(C-C) = 0.006 Å; R factor = 0.033; single-crystal X-ray study; T = 298 K; wR factor = 0.076;

D O I：

10.1107/S1600536812041049

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [In(C11H10N2) Cl-3(C2H6OS)], the In III cation is six-coordinated in a distorted octahedral configuration by two N atoms from the chelating 6-methyl-2,2'-bipyridine ligand, one O atom from a dimethylsulfoxide group and three Cl- anions. Weak intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot Cl hydrogen bonds and intramolecular C-H center dot center dot center dot Cl hydrogen bonds are present in the structure.

引用

页码：M1327 / +

页数：10

共 21 条

[1]

Abedi A., 2012, Z KRIST-NEW CRYST ST, V227, P169

[2] Indium(III) complexes containing bithiazole derivatives, chloride, methanol, and dimethyl sulfoxide: X-ray studies, spectroscopic characterization, and thermal analyses [J].

Abediy, Anita ;

Safari, Nasser ;

Amaniz, Vahid ;

Khavasiz, Hamid Reza .

JOURNAL OF COORDINATION CHEMISTRY, 2012, 65 (02) :325-338

[3] Trichlorido(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)(dimethyl sulfoxide-κO)indium(III) [J].

Ahmadi, Roya ;

Kalateh, Khadijeh ;

Abedi, Anita ;

Amani, Vahid ;

Khavasi, Hamid Reza .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M1306-U781

[4] Dichlorido(6-methyl-2,2′-bipyridine k2N,N′)zinc(II) [J].

Ahmadi, Roya ;

Kalateh, Khadijeh ;

Ebadi, Amin ;

Amani, Vahid ;

Khavasi, Hamid Reza .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M1266-U473

[5] Tetrakis(6-methyl-2,2′-bipyridine)-1κ2N,N′;2κ2N,N′;3κ2N,N′;4κ2N,N′-tetra-μ-nitrato-1:2κ2O:O′;2:3κ3O:O′,O";2:3κ3O,O′:O";3:4κ2O:O′-tetranitrato-1κ4O,O′;4κ2O,O′-tetralead(II) [J].

Ahmadi, Roya ;

Kalateh, Khadijeh ;

Alizadeh, Robabeh ;

Khoshtarkib, Zeinab ;

Amani, Vahid .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 :M1169-+

[6] Dichlorido(6-methyl-2,2′-bipyridine-κ2N,N′)mercury(II) [J].

Ahmadi, Roya ;

Ebadi, Amin ;

Kalateh, Khadijeh ;

Norouzi, Ali ;

Amani, Vahid .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M1407-U551

[7] Synthesis, characterization and crystal structure determination of platinum(IV) complexes containing, bipyridine derivatives and chloride, [Pt(5,5′-dmbipy)Cl4] and [Pt(6-mbipy)Cl4] [J].

Amani, Vahid ;

Safari, Nasser ;

Khavasi, Hamid Reza ;

Akkurt, Mehmet .

POLYHEDRON, 2009, 28 (14) :3026-3030

[8]

Bruker, 2001, SADABS

[9]

Bruker, 2007, APEX2 SAINT

[10]

ILYUKHIN AB, 1994, KRISTALLOGRAFIYA+, V39, P439

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