DRAG ON A TETHERED CHAIN MOVING IN A POLYMER MELT

被引:0
作者
AJDARI, A
BROCHARDWYART, F
GAY, C
DEGENNES, PG
VIOVY, JL
机构
[1] INST PIERRE & MARIE CURIE,PSI,F-75231 PARIS 05,FRANCE
[2] COLL FRANCE,F-75231 PARIS 05,FRANCE
来源
JOURNAL DE PHYSIQUE II | 1995年 / 5卷 / 04期
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中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
A chain of N monomers is attached to a small colloidal particle, and is pulled (at a velocity V) inside a polymer melt (chemically identical, with P monomers per chain). The main parameter for this problem is the number X(V) of P chains entangled with the (N) chain. Earlier estimates of X are criticized, and a new form is proposed: at large N(N > N-e(2)), we are led to a ''Stokes'' regime, X = N-1/2, while at smaller N (N < N-e(2)), we find a ''Rouse'' regime, X = N/N-e (where N-e is the number of monomers per entanglement).
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页码:491 / 495
页数:5
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