NUCLEOPHILIC-ADDITION TO OLEFINS .15. SOLVENT AND SUBSTITUENT EFFECTS ON THE HYDROLYSIS OF BENZYLIDENEMALONONITRILES IN BASIC ME2SO-WATER SOLUTIONS

被引：25
作者：
BERNASCONI, CF
FOX, JP
KANAVARIOTI, A
PANDA, M
机构：
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1986年 / 108卷 / 09期
关键词：
D O I：
10.1021/ja00269a039
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
引用
收藏
页码：2372 / 2381
页数：10
相关论文
共 39 条
[1]   THE PRINCIPLE OF IMPERFECT SYNCHRONIZATION .1. IONIZATION OF CARBON ACIDS [J].
BERNASCONI, CF .
TETRAHEDRON, 1985, 41 (16) :3219-3234
[2]   NUCLEOPHILIC-ADDITION TO OLEFINS .5. REACTION OF 1,1-DINITRO-2,2-DIPHENYLETHYLENE WITH WATER AND HYDROXIDE ION IN 50-PERCENT ME2SO-50-PERCENT WATER - COMPLETE KINETIC-ANALYSIS OF HYDROLYTIC CLEAVAGE OF THE C=C DOUBLE-BOND IN ACIDIC AND BASIC SOLUTION [J].
BERNASCONI, CF ;
CARRE, DJ ;
KANAVARIOTI, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (16) :4850-4860
[3]   NUCLEOPHILIC-ADDITION TO OLEFINS .12. SOLVENT-INDUCED CHANGE IN THE RATE-LIMITING STEP OF THE HYDROLYSIS OF BENZYLIDENEMALONONITRILE IN ACIDIC ME2SO-WATER SOLUTION [J].
BERNASCONI, CF ;
KANAVARIOTI, A ;
KILLION, RB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (12) :3612-3620
[4]   NUCLEOPHILIC-ADDITION TO OLEFINS .14. KINETICS OF THE REACTION OF 1,3-INDANDIONE ANION WITH BENZYLIDENE-1,3-INDANDIONE [J].
BERNASCONI, CF ;
LAIBELMAN, A ;
ZITOMER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (23) :6570-6575
[5]   NUCLEOPHILIC-ADDITION TO OLEFINS .13. KINETICS OF HYDROLYSIS OF BENZYLIDENE-1,3-INDANDIONE [J].
BERNASCONI, CF ;
LAIBELMAN, A ;
ZITOMER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (23) :6563-6570
[6]   WHEN IS INTRAMOLECULAR PROTON-TRANSFER BETWEEN CARBON AND NITROGEN OR OXYGEN OBSERVABLE [J].
BERNASCONI, CF ;
HIBDON, SA ;
MCMURRY, SE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (12) :3459-3471
[7]   NUCLEOPHILIC-ADDITION TO ACTIVATED OLEFINS .3. REACTIONS OF PIPERIDINE AND MORPHOLINE WITH BENZYLIDENEMALONONITRILE IN 50-PERCENT DIMETHYL SULFOXIDE-50-PERCENT WATER - INTRINSIC BARRIERS IN NUCLEOPHILIC ADDITIONS [J].
BERNASCONI, CF ;
FOX, JP ;
FORNARINI, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (08) :2810-2816
[8]   NUCLEOPHILIC-ADDITION TO OLEFINS .6. STRUCTURE REACTIVITY RELATIONSHIPS IN THE REACTIONS OF SUBSTITUTED BENZYLIDENE MELDRUMS ACIDS WITH WATER, HYDROXIDE ION, AND ARYL OXIDE IONS [J].
BERNASCONI, CF ;
LEONARDUZZI, GD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (19) :5133-5142
[9]   NUCLEOPHILIC-ADDITION TO OLEFINS .2. REACTION OF BENZYLIDENE MELDRUMS ACID WITH WATER, HYDROXIDE ION, AND ARYLOXIDE IONS - COMPLETE KINETIC-ANALYSIS OF THE HYDROLYTIC CLEAVAGE OF THE C=C DOUBLE-BOND [J].
BERNASCONI, CF ;
LEONARDUZZI, GD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (04) :1361-1366
[10]   THE ROLE OF SOLVENT REORGANIZATION IN PROTON-TRANSFER AND NUCLEOPHILIC-ADDITION REACTIONS [J].
BERNASCONI, CF .
PURE AND APPLIED CHEMISTRY, 1982, 54 (12) :2335-2348
1234