ETA-ARENE COMPLEXES OF SCANDIUM(0) AND SCANDIUM(II)

被引：48

作者：

CLOKE, FGN ^{[1
]}

KHAN, K ^{[1
]}

PERUTZ, RN ^{[1
]}

机构：

[1] UNIV YORK,DEPT CHEM,YORK YO1 5DD,N YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 19期

关键词：

D O I：

10.1039/c39910001372

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cocondensation of scandium vapour with 1,3,5-tri-tert-butylbenzene affords the first example of a scandium(0) complex, the sandwich compound bis(eta-1,3,5-tri-tert-butylbenzene)scandium; ESR and UV studies also the reveal the presence of a second compound from this reaction, formulated as a similarly unique example of scandium(II) arising from activation of one of the methyl groups of a tert-butyl ring substituent.

引用

收藏

页码：1372 / 1373

页数：2

相关论文

共 6 条

[1] ON THE STABILITY AND BONDING IN BIS(ETA-ARENE)LANTHANIDE COMPLEXES [J].

ANDERSON, DM ;

CLOKE, FGN ;

COX, PA ;

EDELSTEIN, N ;

GREEN, JC ;

PANG, T ;

SAMEH, AA ;

SHALIMOFF, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (01) :53-55

[2] SYNTHESIS OF BIS(ETA-1,3,5-TRI-T-BUTYLBENZENE) SANDWICH COMPLEXES OF YTTRIUM(0) AND GADOLINIUM(0) - THE X-RAY CRYSTAL-STRUCTURE OF THE 1ST AUTHENTIC LANTHANIDE(0) COMPLEX, [GD(ETA-BUT3C6H3)2] [J].

BRENNAN, JG ;

CLOKE, FGN ;

SAMEH, AA ;

ZALKIN, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (21) :1668-1669

[3]

CLOKE FGN, 1989, POLYHEDRON, V8, P1641

[4] BIS(ETA-PENTAMETHYLCYCLOPENTADIENYL) COMPLEXES OF MOLYBDENUM, TUNGSTEN AND RHENIUM VIA METAL VAPOR SYNTHESIS [J].

CLOKE, FGN ;

DAY, JP ;

GREEN, JC ;

MORLEY, CP ;

SWAIN, AC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, :789-796

[5] SYNTHESIS OF ZEROVALENT BIS(ETA-ARENE) COMPOUNDS OF ZIRCONIUM, HAFNIUM, NIOBIUM, TANTALUM, AND TUNGSTEN USING THE METAL VAPORS [J].

CLOKE, FGN ;

GREEN, MLH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (09) :1938-1943

[6] ACTIVATION OF SP3 CARBON-HYDROGEN BONDS OF ALKYLBENZENES BY RHENIUM FORMING BINUCLEAR MU-ARYLIDENE DERIVATIVES [J].

CLOKE, FGN ;

DEROME, AE ;

GREEN, MLH ;

OHARE, D .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (22) :1312-1313