Bis(2-{[(9H-fluoren-2-yl)methylidene]-amino}phenolato-kappa N-2,O)zinc methanol disolvate

被引:6
作者
Kim, Young-Inn [1 ,2 ]
Yun, Sung-Jae [1 ,2 ]
Hwang, Inn-Hye [1 ,2 ]
Kim, Dae-Young [1 ,2 ]
Kang, Sung Kwon [3 ]
机构
[1] Pusan Natl Univ, Dept Chem Educ, Busan 609735, South Korea
[2] Pusan Natl Univ, Interdisciplinary Program Adv Informat & Display, Busan 609735, South Korea
[3] Chungnam Natl Univ, Dept Chem, Taejon 305764, South Korea
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
基金
新加坡国家研究基金会;
关键词
D O I
10.1107/S160053681201272X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Zn(C20H14NO)(2)]center dot 2CH(3)OH, the Zn-II atom lies on a crystallographic twofold rotation axis and is coordinated by two O atoms and two N atoms from two bidentate 2-{[(9H-fluoren-2-yl)methylidene]amino}phenolate ligands within a distorted tetrahedral geometry. The dihedral angle between the two chelate rings is 82.92 (5)degrees. In the coordinated ligand, the phenol ring is twisted at 30.22 (9)degrees from the mean plane of the fluorene ring. In the crystal, O-H center dot center dot center dot O hydrogen bonds link the complex molecules to the methanol solvent molecules.
引用
收藏
页码:M504 / +
页数:8
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