ELECTROCHEMICAL DOPING OF POLY(3-VINYLPERYLENE) AND ELECTRICAL-PROPERTIES OF DOPED POLYMERS

被引：14
作者：
JEON, IR
NOMA, N
CLARIDGE, RFC
SHIROTA, Y
机构：
[1] Department of Applied Chemistry, Osaka University, Suita
[2] Department of Applied Chemistry, Osaka University, Osaka
[3] Chemistry Department, University of Canterbury, Christchurch
来源：
POLYMER JOURNAL | 1992年 / 24卷 / 03期
关键词：
POLY(3-VINYLPERYLENE); ELECTROCHEMICAL DOPING; ELECTROCHEMICALLY-DOPED POLYMER; RADICAL CATION; ELECTRICAL CONDUCTIVITY; ACTIVATION ENERGY;
D O I：
10.1295/polymj.24.273
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(3-vinylperylene) has been prepared by radical polymerization of 3-vinylperylene, and characterized by spectroscopic methods, mol. wt. determination, and differential scanning calorimetry. Electrochemical doping of poly(3-vinylperylene), and characterization and electrical properties of doped polymers have been studied. Electrochemically-doped poly(3-vinylperylene) is identified as a partially oxidized radical-cation salt with ClO4- as a dopant. The polymer with a doping degree of 86% exhibits a room-temperature conductivity of 1 x 10(-5) S cm-1 and an activation energy of ca. 0.4 eV. The presence of hole charge carriers is shown from the electron spin resonance spectrum.
引用
收藏
页码：273 / 279
页数：7
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