2 OPTICALLY-ACTIVE LUTEOCHROMES - PREPARATION, SPECTRA, AND CHIROPTICAL AND CHROMATOGRAPHIC PROPERTIES

被引：6
作者：
ACEMOGLU, M [1 ]
EUGSTER, CH [1 ]
机构：
[1] UNIV ZURICH, INST ORGAN CHEM, WINTERTHURERSTR 190, CH-8057 ZURICH, SWITZERLAND
来源：
HELVETICA CHIMICA ACTA | 1984年 / 67卷 / 08期
关键词：
D O I：
10.1002/hlca.19840670826
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Selective rearrangement of (5R,6S,5''R,6''S)-5,6:5'',6''-diepoxy-5,6,5'',6''-tetrahydro-.beta.,.beta.-carotene with the aid of an ethereal solution of malonic acid leads to the mixture of the C(8'')-epimeric luteochromes. HPLC [high performance liquid chromatography] separation gave the pure isomers. This is the 1st report on the preparation of optically active luteochromes.
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页码：2226 / 2230
页数：5
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