GAS-PHASE HYDROFORMYLATION OF PROPYLENE ON RU/SIO2 CATALYSTS

被引：5
|
作者：
HALLIGUDI, SB
KHAN, MMT
MOROZ, BL
CHUVILIN, AL
PROSVIRIN, IP
LIKHOLOBOV, VA
机构：
[1] CENT SALT & MARINE CHEM RES INST,BHAVNAGAR 364002,INDIA
[2] NOVOSIBIRSK CATALYSIS INST,NOVOSIBIRSK 630090,USSR
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1991年 / 44卷 / 01期
关键词：
D O I：
10.1007/BF02068397
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ru/SiO2 catalysts prepared by reduction of supported RuCl3. x H2O are active in gas-phase hydroformylation of propylene at low pressure (ca. 0.3 MPa) of H-2 + CO + C3H6 mixtured and show unexpectedly high selectivity towards unbranched oxo-products. Data concerning the effect of electronic state and dispersity of Ru on their catalytic behavior have been obtained.
引用
收藏
页码：139 / 146
页数：8
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