DYNAMICS OF PROTON-TRANSFER IN SOLUTION BY NMR RELAXATION

被引：14
|
作者：
LATANOWICZ, L
机构：
[1] A. Mickiewicz Univ, Poznan, Pol, A. Mickiewicz Univ, Poznan, Pol
来源：
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1987年 / 91卷 / 03期
关键词：
DEUTERIUM - Mixing - NUCLEAR MAGNETIC RESONANCE - Measurements - PROTONS - WATER - Mixing;
D O I：
10.1002/bbpc.19870910314
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The expression has been derived for the rate of intramolecular part of the relaxation induced by the motion of nuclei transferred between the two sites of unequal energy and by isotropic reorientation of nuclear pairs. This expression should be useful in analyzing T//1 data for hydrogen bonded liquids. The relaxation time T//1 of protons in H//2 O-D//2O mixtures has been measured and analyzed on the basis of the presented theory.
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页码：237 / 242
页数：6
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