C-2 DIAMINE, PSEUDO-C-2 POLY(AMIDE) AND POLY(UREA) AS CHIRAL INDUCTORS IN ASYMMETRIC CATALYSIS

被引：74

作者：

GAMEZ, P

DUNJIC, B

FACHE, F

LEMAIRE, M

机构：

[1] INST RECH CATALYSE,CATALYSE & SYNTH ORGAN LAB,F-69622 VILLEURBANNE,FRANCE

[2] UNIV LYON 1,ESCIL,F-69622 VILLEURBANNE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 12期

关键词：

D O I：

10.1039/c39940001417

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral C-2 diamine, poly(amide) and poly(urea) act as inductors both in asymmetric hydride transfer reduction of acetophenone and carbon-carbon bond formation with high enantioselectivity of up to 95% enantiomeric excess.

引用

页码：1417 / 1418

页数：2

共 14 条

[1] CHIRAL POLYMER CATALYSTS IN PREPARATIVE ORGANIC-CHEMISTRY - A CRITICAL OVERVIEW [J].

AGLIETTO, M ;

CHIELLINI, E ;

DANTONE, S ;

RUGGERI, G ;

SOLARO, R .

PURE AND APPLIED CHEMISTRY, 1988, 60 (03) :415-430

[2] POLY-L-LEUCINE AS AN ADDED CHIRAL LIGAND FOR THE PALLADIUM CATALYZED CARBONYLATION OF ALLYLIC ALCOHOLS [J].

ALPER, H ;

HAMEL, N .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (02) :135-136

[3]

BABA N, 1978, TETRAHEDRON LETT, V44, P4281

[4]

BEAMER RL, 1969, J PHARM SCI, P1419

[5] NEW RHODIUM COMPLEXES ANCHORED ON MODIFIED USY ZEOLITES - A REMARKABLE EFFECT OF THE SUPPORT ON THE ENANTIOSELECTIVITY OF CATALYTIC-HYDROGENATION OF PROCHIRAL ALKENES [J].

CORMA, A ;

IGLESIAS, M ;

DELPINO, C ;

SANCHEZ, F .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (18) :1253-1255

[6]

GAMEZ P, 1993, TETRAHEDRON LETT, P6897

[7]

INOUE S, 1978, MAKROMOL CHEM, V180, P480

[8] "Synthetic Enzymes". Highly Stereoselective Epoxidation of Chalcone in a Triphasic Toluene-Water-Poly[(S)-alanine] System [J].

Julia, S. ;

Vega, J. C. .

AFINIDAD, 2024, 81 (603) :929-931

[9]

KIM BM, 1990, TETRAHEDRON LETT, V31, P3003

[10]

MANGENEY P, 1988, SYNTHESIS-STUTTGART, P255

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