INTRAMOLECULAR ELECTRON-TRANSFER ACROSS POLYENEBRIDGES

被引：3

作者：

THOMAS, JA

JONES, CJ

HAMOR, TA

MCCLEVERTY, JA

MABBS, F

COLLISON, D

HARDING, C

机构：

[1] UNIV BRISTOL,BRISTOL BS8 1TH,AVON,ENGLAND

[2] OPEN UNIV,MILTON KEYNES MK7 6AA,BUCKS,ENGLAND

[3] UNIV MANCHESTER,MANCHESTER M13 9PL,LANCS,ENGLAND

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1993年 / 234卷

关键词：

D O I：

10.1080/10587259308042903

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The new bipyridylpolyene bridged bimetallic complexes [{LMo(NO)Cl}NC5H5-(C2H2)n-C5H5N] (n = 2-4 all trans) have been synthesised along with their monometallic counterpart [{LMo(NO)Cl}NC5H5-(C2H2)n-C5H5N]. All of the bimetallic complexes exhibit EPR spectra consistent with fast electron exchange between the metal centres and may be reduced in two 1-electron processes, the separation between which decreases by approximately 166 mV per additional ethenyl unit.

引用

页码：103 / 108

页数：6

共 12 条

[1] THE FORMATION OF AMINE AND AMIDE COMPLEXES IN THE REACTIONS BETWEEN [MO(NO)(HB(3,5-ME2C3N2H)3)CL2)] [MO(NO)(HB(3,5-ME2C3N2H)3)I2] AND SATURATED CYCLIC AMINES - THE MOLECULAR-STRUCTURES OF [MO(NO)(HB(3,5-ME2C3N2H)3)I(NHC5H10)] AND [MO(NO)(HB(3,5-ME2C3N2H)3)I(NC4H8)] [J].