SOLUTION STRUCTURE OF 5-COORDINATE COMPLEXES OF RUTHENIUM(II) - EVIDENCE FOR A SQUARE-PYRAMIDAL GEOMETRY FOR THE CATIONS [RUHPME2PH4]+, [RUC2PHPME2PH4]+

被引：17

作者：

ASHWORTH, TV ^{[1
]}

CHALMERS, AA ^{[1
]}

SINGLETON, E ^{[1
]}

机构：

[1] CSIR,NATL CHEM RES LAB,PRETORIA 0001,SOUTH AFRICA

来源：

INORGANIC CHEMISTRY | 1985年 / 24卷 / 14期

关键词：

D O I：

10.1021/ic00208a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：2125 / 2126

页数：2

共 18 条

[1] SYNTHESIS AND REARRANGEMENT REACTIONS OF DIHALOGENOTRIS-(TERTIARY PHOSPHINE)RUTHENIUM(II) AND DIHALOGENOTETRAKIS-(TERTIARY PHOSPHINE)RUTHENIUM(II) COMPOUNDS [J].

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[2] IONIC RUTHENIUM(IV) TRIHYDRIDES AS INTERMEDIATES IN HETEROLYTIC FISSION OF DIHYDROGEN BY 5-CO-ORDINATE HYDRIDORUTHENIUM(II) CATIONS - DIRECT EVIDENCE FOR AN OXIDATIVE ADDITION-REDUCTIVE ELIMINATION PATHWAY [J].

ASHWORTH, TV ;

SINGLETON, E .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1976, (18) :705-706

[3] STABLE CATIONIC MONOALKYLCARBONATE COMPLEXES OF RUTHENIUM(II) FROM REACTIONS OF CO-2 WITH ALCOHOL SOLUTIONS OF RUTHENIUM HYDRIDES [J].

ASHWORTH, TV ;

SINGLETON, E .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1976, (06) :204-205

[4] CATIONIC RUTHENIUM SYSTEMS .2. SYNTHESIS, CHARACTERIZATION, AND X-RAY STRUCTURE OF HYDRIDOPENTAKIS(DIMETHYLPHENYLPHOSPHINE)-RUTHENIUM(II) HEXAFLUOROPHOSPHATE - DISCUSSION OF EFFECTS OF STERIC STRAINS ON REACTIVITY OF COMPLEX [J].

ASHWORTH, TV ;

NOLTE, MJ ;

SINGLETON, E .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (19) :1816-1822

[5]

ASHWORTH TV, UNPUB

[6] X-RAY CRYSTAL-STRUCTURE OF TRANS-CHLOROHYDRIDOBIS(DIOP)RUTHENIUM(II) - OCTAHEDRAL COMPLEX WITH INEQUIVALENT PHOSPHORUS ATOMS [J].

BALL, RG ;

JAMES, BR ;

TROTTER, J ;

WANG, DKW ;

DIXON, KR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (10) :460-461

[7] OCTAHEDRAL AND TRIGONAL-BIPYRAMIDAL COMPLEXES OF RUTHENIUM(II) WITH BIDENTATE PHOSPHINE-LIGANDS [J].

BRIGGS, JC ;

MCAULIFFE, CA ;

DYER, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (03) :423-427

[8] PREPARATION AND REACTIONS OF HYDRIDOCHLOROTRIS(TRIPHENYLPHOSPHINE)-RUTHENIUM(2) INCLUDING HOMOGENEOUS CATALYTIC HYDROGENATION OF ALK-1-ENES [J].

HALLMAN, PS ;

MCGARVEY, BR ;

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JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (12) :3143-+

[9] SOLUTION STRUCTURE AND DYNAMICS OF 5-COORDINATE D6 COMPLEXES [J].

HOFFMAN, PR ;

CAULTON, KG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (15) :4221-4228

[10] HYDRIDO-DITERTIARY PHOSPHINE, DITERTIARY-ARSINE, AND DITERTIARY-CHIRAL PHOSPHINE COMPLEXES OF RUTHENIUM(II) [J].

JAMES, BR ;

WANG, DKW .

INORGANICA CHIMICA ACTA, 1976, 19 (02) :L17-L18

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