THE SUBMILLIMETER ROTATION-TUNNELING SPECTRUM OF AR-D2O AND AR-NH3

被引：49
|
作者：
ZWART, E
MEERTS, WL
机构：
[1] Fysisch Laboratorium, University of Nijmegen, 6525 ED Nijmegen, Toernooiveld
来源：
CHEMICAL PHYSICS | 1991年 / 151卷 / 03期
关键词：
D O I：
10.1016/0301-0104(91)80025-D
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two bands for Ar-D2O and one band for Ar-NH3 have been observed for the first time in the frequency region 300-500 GHz. For both complexes the bands are explained in terms of a nearly free internal rotor model, following earlier investigations of these types of complexes. We found evidence that this model is correct for Ar-D2O. Two of the internal rotor states studied for the Ar-D2O complex show a Coriolis interaction and the interaction constant is determined. The hyperfine constants for the studied excited state of the Ar-NH3 complex turn out to be large.
引用
收藏
页码：407 / 418
页数：12
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