Crystal structure of tetrakisdiphenylammonium hexadecachlorotetrabismuthate(III)

被引：5
作者：
AlFarhan, KA
AlWassil, AI
机构：
[1] Department of Chemistry, College of Science, King Saud University, Riyadh
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1995年 / 25卷 / 12期
关键词：
crystal structure; bismuth chloride complexes; diphenylammonium;
D O I：
10.1007/BF01671080
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
[(C6H5)(2)NH2](+)(4)[Bi4Cl16](4-) crystallizes in the triclinic space group P1 with a = 11.835(2), b = 12.393(2), c = 12.625(3)Angstrom, alpha = 108.37(3), beta = 108.69(3), gamma = 95.00(3)degrees and D-c = 2.135 g cm(-3) for Z = 1. The [Bi4Cl16](4-) anion is a centrosymmetric cluster of four distorted edge-sharing BiCl6 octahedra. The ranges of the Bi-Cl bonds are 2.484(4) - 2.605(3)Angstrom for Bi-Cl(terminal), 2.691(3)-2.956(4)Angstrom for Bi-Cl(mu(2)) and 2.960(3) - 3.120(4)Angstrom for Bi-Cl(mu(3)), The cations and anions are held in place by weak hydrogen bonds.
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页码：841 / 844
页数：4
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