SUBSTRATE-SPECIFIC CATALYSIS BY ION-PAIRS

被引：30

作者：

SMITH, PJ ^{[1
]}

KIM, EI ^{[1
]}

WILCOX, CS ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 11期

关键词：

D O I：

10.1002/anie.199316481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rate accelerations up to 400‐fold are observed for the reaction of amine 1 with 1‐chloro‐2,4‐dinitrobenzene in CHCl3 to give 3 when simple ion pairs like tetrabutylammonium tosylate (or benzylate) are added. The exact reaction mechanism is not yet known. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1648 / 1650

页数：3

共 43 条

[1] MANIPULATING THE STOICHIOMETRY AND STRENGTH OF PHOSPHODIESTER BINDING TO A BISGUANIDINE CLEFT IN DMSO WATER SOLUTIONS
ARIGA, K
ANSLYN, EV
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (02) : 417 - 420
[2] BENDER ML, 1984, BIOORGANIC CHEM ENZY, P287
[3] CATALYTIC CYCLOPHANES .5. CATALYTIC CYCLOPHANES - A PORPHYRIN-BRIDGED CYCLOPHANE AS A MODEL FOR CYTOCHROME-P-450 ENZYMES
BENSON, DR
VALENTEKOVICH, R
DIEDERICH, F
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (02): : 191 - 193
[4] BENSON DR, 1990, ANGEW CHEM, V102, P213
[5] Bernasconi C. F., 1973, MTP INT REV SCI OR 1, V3, P33
[6] INTERMEDIATES IN NUCLEOPHILIC AROMATIC-SUBSTITUTION .20. RATE-LIMITING PROTON-TRANSFER IN THE FORMATION OF MEISENHEIMER COMPLEXES BETWEEN 1,3,5-TRINITROBENZENE AND AMINES - EFFECT OF DIMETHYL-SULFOXIDE ON PROTON-TRANSFER RATES - RELATIVE LEAVING-GROUP ABILITIES OF AMINES AND ALKOXIDE IONS
BERNASCONI, CF
MULLER, MC
SCHMID, P
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (18) : 3189 - 3196
[7] VERY FAST ESTER HYDROLYSIS BY A CYCLODEXTRIN DIMER WITH A CATALYTIC LINKING GROUP
BRESLOW, R
ZHANG, BL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) : 5882 - 5883
[8] CYCLODEXTRIN-B12, A POTENTIAL ENZYME COENZYME MIMIC
BRESLOW, R
DUGGAN, PJ
LIGHT, JP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (10) : 3982 - 3983
[9] BURROWS CJ, 1990, INCLUSION PHENOMENA, P199
[10] INTRAMOLECULAR CATALYSIS IN THE ENOLIZATION OF BETA-PIPERIDINOPROPIOPHENONE AND ITS METHIODIDE DERIVATIVE
COX, BG
DEMARIA, P
FINI, A
HASSAN, AF
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1981, (10): : 1351 - 1357

← 1 2 3 4 5 →