THE INFLUENCE OF SPECIFIC IMPURITIES ON THE NUCLEATION AND GROWTH OF MAGNETITE DURING REDUCTION OF ARTIFICIALLY PREPARED HEMATITE

被引:9
作者
CHAIGNEAU, R
HEEREMA, RH
机构
[1] Department of Raw Materials Technology, Delft University of Technology, Delft
来源
METALLURGICAL TRANSACTIONS B-PROCESS METALLURGY | 1991年 / 22卷 / 04期
关键词
D O I
10.1007/BF02654289
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The influence of traces of specifically added impurity oxides on the reduction behavior of hematite to magnetite has been investigated. Oxides of Al, Ca, Mg, or Si have a direct influence on the nucleation and growth of the magnetite. To distinguish between these nucleation and growth phenomena on the basis of the reduction rate, the nucleation model of Avrami-Erofeyev has been used. Cracking of the magnetite was observed, which was found to depend on the nature and amount of added impurities. Explanations based on mineralogical data are presented for the observed behavior.
引用
收藏
页码:503 / 511
页数:9
相关论文
共 33 条
[1]   Granulation, Phase Change, and Microstructure - Kinetics of Phase Change. III [J].
Avrami, M .
JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (02) :177-184
[2]   Kinetics of phase change I - General theory [J].
Avrami, M .
JOURNAL OF CHEMICAL PHYSICS, 1939, 7 (12) :1103-1112
[3]  
Avrami M., 1940, J CHEM PHYS, V8, P212, DOI DOI 10.1063/1.1750631
[4]   THE CONDITIONS FOR THE FORMATION OF LATH AND POROUS MAGNETITE ON REDUCTION OF HEMATITE IN H-2/H2O GAS-MIXTURES [J].
BAGULEY, P ;
STJOHN, DH ;
HAYES, PC .
METALLURGICAL TRANSACTIONS B-PROCESS METALLURGY, 1983, 14 (03) :513-514
[5]  
BARO R, 1968, ADV XRAY ANAL, V11, P473
[6]  
BOLDYREV VV, 1979, CONTROL REACTIVITY S, P15
[7]   STRUCTURAL-CHANGES AND KINETICS IN GASEOUS REDUCTION OF HEMATITE [J].
BRADSHAW, AV ;
MATYAS, AG .
METALLURGICAL TRANSACTIONS B-PROCESS METALLURGY, 1976, 7 (01) :81-87
[8]  
CHRISTIAN JW, 1975, THEORY TRANSFORMATIO, P418
[9]  
DEBRUIJN W, 1990, THESIS DELFT U PRESS, P47
[10]  
DEBRUIJN W, 1989, MINER METALL PROC, P43